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 SM ISO690:2012NOVITSKY, Ghenadie, COSTES, Jean-Pierre, POPOVSKI, L., SHOVA, Sergiu, GULYA, Aurelian. Magnetic investigation of an unusual dissymmetric binuclear manganese carboxylate complex. In: Chemistry Journal of Moldova, 2006, nr. 1(1), pp. 97-99. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2006.01(1).03 |
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| Chemistry Journal of Moldova | ||||||
| Numărul 1(1) / 2006 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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| DOI:https://doi.org/10.19261/cjm.2006.01(1).03 | ||||||
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The magnetic susceptibility (χT) of an unusual dissymmetric binuclear manganese corboxylate complex has been measured from 2 to 300K. The magnetic data which have been fitted with help of the Heisenberg Dirac Van Vleck HDVV spin-exchange Hamiltonian
H = −J S1S2ur ur, indicate that an antiferromagnetic interaction equal to J = -0.90(1) cm-1 is present. A correlation between J values and Mn-H2 O-Mn angles has been tempted.
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| Cuvinte-cheie manganese(II) carboxylates, magnetic properties |
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Dublin Core Export
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Noviţchi, G.V.</dc:creator> <dc:creator>Costes, J.</dc:creator> <dc:creator>Popovschi, L.</dc:creator> <dc:creator>Şova, S.G.</dc:creator> <dc:creator>Gulea, A.P.</dc:creator> <dc:date>2006-09-27</dc:date> <dc:description xml:lang='en'>The magnetic susceptibility (χT) of an unusual dissymmetric binuclear manganese corboxylate complex has been measured from 2 to 300K. The magnetic data which have been fitted with help of the Heisenberg Dirac Van Vleck HDVV spin-exchange Hamiltonian H = −J S1S2ur ur, indicate that an antiferromagnetic interaction equal to J = -0.90(1) cm-1 is present. A correlation between J values and Mn-H2 O-Mn angles has been tempted. </dc:description> <dc:identifier>10.19261/cjm.2006.01(1).03</dc:identifier> <dc:source>Chemistry Journal of Moldova 1 (1) 97-99</dc:source> <dc:subject>manganese(II) carboxylates</dc:subject> <dc:subject>magnetic properties</dc:subject> <dc:title>Magnetic investigation of an unusual dissymmetric binuclear manganese carboxylate complex</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>
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