Crystal structures of 2-formyl-6-methyl- and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazones
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CHUMAKOV, Yurii, TSAPKOV, Victor I., ANTOSYAK, Boris, SIMONOV, Yurii A., IANELLI, Sandra, BAIRAK, N., GULYA, Aurelian, PALOMARES-SÁNCHEZ, S.. Crystal structures of 2-formyl-6-methyl- and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazones. In: Crystallography Reports, 2011, vol. 56, pp. 136-140. ISSN 1063-7745. DOI: https://doi.org/10.1134/S1063774510061033
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Crystallography Reports
Volumul 56 / 2011 / ISSN 1063-7745 /ISSNe 1562-689X

Crystal structures of 2-formyl-6-methyl- and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazones

DOI:https://doi.org/10.1134/S1063774510061033

Pag. 136-140

Chumakov Yurii1, Tsapkov Victor I.2, Antosyak Boris1, Simonov Yurii A.1, Ianelli Sandra3, Bairak N.2, Gulya Aurelian2, Palomares-Sánchez S.4
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 Moldova State University,
3 IMEM-CNR Institute of Materials for Electronics and Magnetism-National Council for Research ,
4 Universidad Politécnica de San Luis Potosí
 
 
Disponibil în IBN: 20 ianuarie 2024


Rezumat

New thiosemicarbazones-2-formyl-6-methylpyridine 4-phenylthiosemicarbazone (I) and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazone hydrate (II)-were synthesized and their structures were determined. Molecules I and II are nonplanar, the phenyl moiety at the terminal nitrogen atom being rotated by 19.9° and 39.5°, respectively. The water molecule is the main factor determining the crystal packing of molecules II. 

Cuvinte-cheie
Crystal packings, Methylpyridine, Phenyl moieties, Terminal-nitrogen, Thiosemicarbazones, Water molecule