Crystal structures of 2-formyl-6-methyl- and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazones

Chumakov Yurii; Tsapkov Victor I.; Antosyak Boris; Simonov Yurii A.; Ianelli Sandra; Bairak N.; Gulya Aurelian; Palomares-Sánchez S.

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CHUMAKOV, Yurii, TSAPKOV, Victor I., ANTOSYAK, Boris, SIMONOV, Yurii A., IANELLI, Sandra, BAIRAK, N., GULYA, Aurelian, PALOMARES-SÁNCHEZ, S.. Crystal structures of 2-formyl-6-methyl- and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazones. In: Crystallography Reports, 2011, vol. 56, pp. 136-140. ISSN 1063-7745. DOI: https://doi.org/10.1134/S1063774510061033

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Crystallography Reports

Volumul 56 / 2011 / ISSN 1063-7745 /ISSNe 1562-689X

Crystal structures of 2-formyl-6-methyl- and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazones

DOI:https://doi.org/10.1134/S1063774510061033

Pag. 136-140

Chumakov Yurii¹, Tsapkov Victor I.², Antosyak Boris¹, Simonov Yurii A.¹, Ianelli Sandra³, Bairak N.², Gulya Aurelian², Palomares-Sánchez S.⁴

¹ Institute of Applied Physics, Academy of Sciences of Moldova,
² Moldova State University,
³ IMEM-CNR Institute of Materials for Electronics and Magnetism-National Council for Research ,
⁴ Universidad Politécnica de San Luis Potosí

Disponibil în IBN: 20 ianuarie 2024

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New thiosemicarbazones-2-formyl-6-methylpyridine 4-phenylthiosemicarbazone (I) and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazone hydrate (II)-were synthesized and their structures were determined. Molecules I and II are nonplanar, the phenyl moiety at the terminal nitrogen atom being rotated by 19.9° and 39.5°, respectively. The water molecule is the main factor determining the crystal packing of molecules II.

Cuvinte-cheie
Crystal packings, Methylpyridine, Phenyl moieties, Terminal-nitrogen, Thiosemicarbazones, Water molecule

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