| Conţinutul numărului revistei |
| Articolul precedent |
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 SM ISO690:2012SAMUSI, Nina, GULYA, Aurelian, TSAPKOV, Victor I.. Heteronuclear [copper(II), p-element] complexes containing the N1,N4-bis(salicylidene)isosemicarbazidate ion. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 1997, vol. 23, pp. 874-876. ISSN -. |
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  Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
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| Volumul 23 / 1997 / ISSN - /ISSNe 1070-3284 | ||||||
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| Pag. 874-876 | ||||||
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The heteronuclear [copper(II), p-element] complexes with N1,N4-bis(salicylidene)isosemicarbazide, (C5H12N)CuL · MCl3 · CH3OH (H3L = HOC6H4CH=NN=C(OH)N=CHC6H4OH; M = Bi3+, Sb3+, Ga3+, In3+) and (C5H12N)CuL · SnCl4 are synthesized. It is established that H3L functions as a tetradentate O,N,N,O-ligand. In the coordination compounds, the Cu2+ ion is linked to the p-element ions through the oxygen atoms of the phenolic OH groups of L3-. It is shown that, in the temperature range 30-80°C, the resistivity of the complexes exhibits a temperature dependence typical of semiconductor materials. |
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Dublin Core Export
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Samusi, N.M.</dc:creator> <dc:creator>Gulea, A.P.</dc:creator> <dc:creator>Ţapcov, V.I.</dc:creator> <dc:date>1997-12-12</dc:date> <dc:description xml:lang='en'><p>The heteronuclear [copper(II), p-element] complexes with N<sup>1</sup>,N<sup>4</sup>-bis(salicylidene)isosemicarbazide, (C<sub>5</sub>H<sub>12</sub>N)CuL · MCl<sub>3</sub> · CH<sub>3</sub>OH (H<sub>3</sub>L = HOC<sub>6</sub>H<sub>4</sub>CH=NN=C(OH)N=CHC<sub>6</sub>H<sub>4</sub>OH; M = Bi<sup>3+</sup>, Sb<sup>3+</sup>, Ga<sup>3+</sup>, In<sup>3+</sup>) and (C<sub>5</sub>H<sub>12</sub>N)CuL · SnCl<sub>4</sub> are synthesized. It is established that H<sub>3</sub>L functions as a tetradentate O,N,N,O-ligand. In the coordination compounds, the Cu<sup>2+</sup> ion is linked to the p-element ions through the oxygen atoms of the phenolic OH groups of L<sup>3-</sup>. It is shown that, in the temperature range 30-80°C, the resistivity of the complexes exhibits a temperature dependence typical of semiconductor materials. </p></dc:description> <dc:source>Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya () 874-876</dc:source> <dc:title>Heteronuclear [copper(II), p-element] complexes containing the N1,N4-bis(salicylidene)isosemicarbazidate ion</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>
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