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 SM ISO690:2012SAMUSI, Nina, GULYA, Aurelian, TSAPKOV, Victor I.. Heteronuclear [copper(II), p-element] complexes containing the N1,N4-bis(salicylidene)isosemicarbazidate ion. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 1997, vol. 23, pp. 874-876. ISSN -. |
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  Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
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| Volumul 23 / 1997 / ISSN - /ISSNe 1070-3284 | ||||||
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| Pag. 874-876 | ||||||
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The heteronuclear [copper(II), p-element] complexes with N1,N4-bis(salicylidene)isosemicarbazide, (C5H12N)CuL · MCl3 · CH3OH (H3L = HOC6H4CH=NN=C(OH)N=CHC6H4OH; M = Bi3+, Sb3+, Ga3+, In3+) and (C5H12N)CuL · SnCl4 are synthesized. It is established that H3L functions as a tetradentate O,N,N,O-ligand. In the coordination compounds, the Cu2+ ion is linked to the p-element ions through the oxygen atoms of the phenolic OH groups of L3-. It is shown that, in the temperature range 30-80°C, the resistivity of the complexes exhibits a temperature dependence typical of semiconductor materials. |
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<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xmlns='http://datacite.org/schema/kernel-3' xsi:schemaLocation='http://datacite.org/schema/kernel-3 http://schema.datacite.org/meta/kernel-3/metadata.xsd'> <creators> <creator> <creatorName>Samusi, N.M.</creatorName> <affiliation>Universitatea de Stat din Moldova, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Gulea, A.P.</creatorName> <affiliation>Universitatea de Stat din Moldova, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Ţapcov, V.I.</creatorName> <affiliation>Universitatea de Stat din Moldova, Moldova, Republica</affiliation> </creator> </creators> <titles> <title xml:lang='en'>Heteronuclear [copper(II), p-element] complexes containing the N1,N4-bis(salicylidene)isosemicarbazidate ion</title> </titles> <publisher>Instrumentul Bibliometric National</publisher> <publicationYear>1997</publicationYear> <dates> <date dateType='Issued'>1997-12-12</date> </dates> <resourceType resourceTypeGeneral='Text'>Journal article</resourceType> <descriptions> <description xml:lang='en' descriptionType='Abstract'><p>The heteronuclear [copper(II), p-element] complexes with N<sup>1</sup>,N<sup>4</sup>-bis(salicylidene)isosemicarbazide, (C<sub>5</sub>H<sub>12</sub>N)CuL · MCl<sub>3</sub> · CH<sub>3</sub>OH (H<sub>3</sub>L = HOC<sub>6</sub>H<sub>4</sub>CH=NN=C(OH)N=CHC<sub>6</sub>H<sub>4</sub>OH; M = Bi<sup>3+</sup>, Sb<sup>3+</sup>, Ga<sup>3+</sup>, In<sup>3+</sup>) and (C<sub>5</sub>H<sub>12</sub>N)CuL · SnCl<sub>4</sub> are synthesized. It is established that H<sub>3</sub>L functions as a tetradentate O,N,N,O-ligand. In the coordination compounds, the Cu<sup>2+</sup> ion is linked to the p-element ions through the oxygen atoms of the phenolic OH groups of L<sup>3-</sup>. It is shown that, in the temperature range 30-80°C, the resistivity of the complexes exhibits a temperature dependence typical of semiconductor materials. </p></description> </descriptions> <formats> <format>uri</format> </formats> </resource>
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