Catalytic &quot;triangles&quot;: Binding of iron in task-specific ionic liquids

Prodius Denis; Makaev Fliur; Styngach Evgenia; Pogrebnoi Vsevolod; Meriakre V.; Novitsky Ghenadie; Kostakis George E.; Anson Christopher E.; Powell Annie Katherine

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208

SM ISO690:2012

PRODIUS, Denis, MAKAEV, Fliur, STYNGACH, Evgenia, POGREBNOI, Vsevolod, MERIAKRE, V., NOVITSKY, Ghenadie, KOSTAKIS, George E., ANSON, Christopher E., POWELL, Annie Katherine. Catalytic "triangles": Binding of iron in task-specific ionic liquids. In: Chemical Communications, 2013, vol. 49, pp. 1915-1917. ISSN 1359-7345. DOI: https://doi.org/10.1039/c2cc36741f

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Chemical Communications

Volumul 49 / 2013 / ISSN 1359-7345 /ISSNe 1364-548X

Catalytic "triangles": Binding of iron in task-specific ionic liquids

DOI:https://doi.org/10.1039/c2cc36741f

Pag. 1915-1917

Prodius Denis¹², Makaev Fliur², Styngach Evgenia², Pogrebnoi Vsevolod², Meriakre V.¹, Novitsky Ghenadie²³, Kostakis George E.⁴, Anson Christopher E.¹, Powell Annie Katherine¹⁴

¹ Institute of Inorganic Chemistry, Karlsruhe Institute of Technology,
² Institute of Chemistry of the Academy of Sciences of Moldova,
³ Grenoble High Magnetic Field Laboratory, CNRS, MPG,
⁴ Karlsruhe Institute of Technology, Institute of Nanotechnology

Disponibil în IBN: 17 iulie 2023

Rezumat

A new class of task-specific ionic liquids (ILs) which contain septuply positively charged {Fe₃^IIIO(RCOO)₆L ₃}⁷⁺ triangles has been synthesized and structurally characterized. Such metal-containing ILs can be repeatedly used as alternative catalysts in the synthesis of 2-pyrrolo-3′-yloxindole or the condensation of indoles with various aldehydes.

Cuvinte-cheie
EMTREE drug terms 2 pyrrolo 3' yloxindole, indole derivative, ionic liquid, metal, oxindole, oxygen, pyrrole, silicon dioxide, unclassified drug EMTREE medical terms article, catalysis, Catalyst, gel chromatography, iron binding capacity, melting point, phase transition, temperature