Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide
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GULYA, Aurelian, GRAUR, Vasilii О., ULCHINA, Ianina, BOUROSH, Pavlina, SMAGLII, Vadim, GARBUZ, Olga, TSAPKOV, Victor I.. Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide. In: Russian Journal of General Chemistry, 2021, vol. 91, pp. 98-107. ISSN 1070-3632. DOI: https://doi.org/10.1134/S1070363221010114
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Russian Journal of General Chemistry
Volumul 91 / 2021 / ISSN 1070-3632 /ISSNe 1608-3350

Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide

DOI: https://doi.org/10.1134/S1070363221010114

Pag. 98-107

Gulya Aurelian1, Graur Vasilii О.1, Ulchina Ianina1, Bourosh Pavlina2, Smaglii Vadim3, Garbuz Olga14, Tsapkov Victor I.1
 
1 Moldova State University,
2 Institute of Applied Physics,
3 Institute of Chemistry,
4 Institute of Zoology
 
Proiecte:
 
Disponibil în IBN: 6 aprilie 2021


Rezumat

Abstract: Сopper(II) nitrate reacts in ethanol with 2-(2-hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide H2L in an 1 : 1 molar ratio to form the coordination compound Cu(HL)NO3·H2O. The introduction of amines [imidazole (Im), 3,5-dibromopyridine (3,5-Br2Py), and 4-methylpyridine (4-Pic)] into the reaction mixture in a molar ratio 1 : 1 : 2 leads to the formation of CuA(HL)NO3·nH2O [A = Im, 3,5-Br2Py, 4-Pic; n = 0, 3] complexes. The structure of the obtained compounds was determined by X-ray structural analysis. The synthesized complexes exhibit antimicrobial, antifungal, antioxidant, and anticancer activities. 

Cuvinte-cheie
Amines, anticancer activity, Antimicrobial activity, Cu(II) coordination compounds, salicylaldehyde 4-allylthiosemicarbazone