Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide
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GULEA, Aurelian; GRAUR, Vasilii О.; ULCHINA, Ianina; BOUROSH, Pavlina; SMAGLII, Vadim; GARBUZ, Olga; TSAPKOV, Victor I.. Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide. In: Russian Journal of General Chemistry. 2021, nr. 1(91), pp. 98-107. ISSN 1070-3632.
10.1134/S1070363221010114
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Russian Journal of General Chemistry
Numărul 1(91) / 2021 / ISSN 1070-3632

Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide

DOI: https://doi.org/10.1134/S1070363221010114

Pag. 98-107

Gulea Aurelian1, Graur Vasilii О.1, Ulchina Ianina1, Bourosh Pavlina2, Smaglii Vadim3, Garbuz Olga14, Tsapkov Victor I.1
 
1 State University of Moldova,
2 Institutul de Fizică Aplicată,
3 Institute of Chemistry,
4 Institutul de Zoologie
 
Disponibil în IBN: 6 aprilie 2021


Rezumat

Abstract: Сopper(II) nitrate reacts in ethanol with 2-(2-hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide H2L in an 1 : 1 molar ratio to form the coordination compound Cu(HL)NO3·H2O. The introduction of amines [imidazole (Im), 3,5-dibromopyridine (3,5-Br2Py), and 4-methylpyridine (4-Pic)] into the reaction mixture in a molar ratio 1 : 1 : 2 leads to the formation of CuA(HL)NO3·nH2O [A = Im, 3,5-Br2Py, 4-Pic; n = 0, 3] complexes. The structure of the obtained compounds was determined by X-ray structural analysis. The synthesized complexes exhibit antimicrobial, antifungal, antioxidant, and anticancer activities. 

Cuvinte-cheie
Amines, anticancer activity, Antimicrobial activity, Cu(II) coordination compounds, salicylaldehyde 4-allylthiosemicarbazone