Synthesis, characterization and toxicity evaluation of Cu(II), Mn(II), Co(II), Ni(II), Pd(II) complexes with ligand derived from hydrazinecarbothioamide
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PAHONTU, Elena Mihaela; SOCEA, Laura-Ileana; BARBUCEANU, Stefania-Felicia; ILIES, D.; BADEA, Mihaela; OLARU, Octavian-Tudorel; GULEA, Aurelian; SOCEA, Bogdan; BRATU, Ovidiu Gabriel. Synthesis, characterization and toxicity evaluation of Cu(II), Mn(II), Co(II), Ni(II), Pd(II) complexes with ligand derived from hydrazinecarbothioamide. In: Revista de Chimie. 2018, nr. 11(69), pp. 2959-2963. ISSN 0034-7752.
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Revista de Chimie
Numărul 11(69) / 2018 / ISSN 0034-7752

Synthesis, characterization and toxicity evaluation of Cu(II), Mn(II), Co(II), Ni(II), Pd(II) complexes with ligand derived from hydrazinecarbothioamide


Pag. 2959-2963

Pahontu Elena Mihaela1, Socea Laura-Ileana1, Barbuceanu Stefania-Felicia1, Ilies D.1, Badea Mihaela2, Olaru Octavian-Tudorel1, Gulea Aurelian3, Socea Bogdan1, Bratu Ovidiu Gabriel14
 
1 University of Medicine and Pharmacy “Carol Davilla”, Bucharest,
2 University of Bucharest,
3 State University of Moldova,
4 Central Military Hospital
 
Disponibil în IBN: 13 decembrie 2018


Rezumat

New copper(II), manganese(II), cobalt(II), nickel(II) and palladium(II) complexes, [Cu(L)(X)(H2O)] [X= OAc- (1), Cl- (3), ClO4 - (4)], [M(L)2(H2O)2] [M= Cu2+(2), Mn2+(5)], [M(L)(OAc)(H2O)] [M= Co2+(6), Pd2+(8)], [Ni(L)(OAc)] (7) were synthesized with 2-(5H-dibenzo [a,d][7] annulen-5-ylacetyl)-N-(4-chlorophenyl) hydrazinecarbothioamide (HL). All the metal complexes have been characterized by different physico-chemical techniques like molar conductivity, magnetic susceptibility measurements, electronic and infrared spectral studies, elemental and thermal analysis. The toxicity of newly synthesized compounds was evaluated using the Daphnia magna bioassay.

Cuvinte-cheie
Cobalt(II), Copper(II), Hydrazinecarbothioamide, Manganese(II), Nickel(II) and palladium(II) complexes, Spectral studies, toxicity