Synthesis, characterization and toxicity evaluation of Cu(II), Mn(II), Co(II), Ni(II), Pd(II) complexes with ligand derived from hydrazinecarbothioamide

Pakhontsu E.; Socea Laura-Ileana; Barbuceanu Stefania-Felicia; Ilies D.; Badea Mihaela; Olaru Octavian-Tudorel; Gulya Aurelian; Socea Bogdan; Bratu Ovidiu Gabriel

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PAKHONTSU, E., SOCEA, Laura-Ileana, BARBUCEANU, Stefania-Felicia, ILIES, D., BADEA, Mihaela, OLARU, Octavian-Tudorel, GULYA, Aurelian, SOCEA, Bogdan, BRATU, Ovidiu Gabriel. Synthesis, characterization and toxicity evaluation of Cu(II), Mn(II), Co(II), Ni(II), Pd(II) complexes with ligand derived from hydrazinecarbothioamide. In: Revista de Chimie, 2018, nr. 11(69), pp. 2959-2963. ISSN 0034-7752.

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Revista de Chimie

Numărul 11(69) / 2018 / ISSN 0034-7752

Synthesis, characterization and toxicity evaluation of Cu(II), Mn(II), Co(II), Ni(II), Pd(II) complexes with ligand derived from hydrazinecarbothioamide

Pag. 2959-2963

Pakhontsu E.¹, Socea Laura-Ileana¹, Barbuceanu Stefania-Felicia¹, Ilies D.¹, Badea Mihaela², Olaru Octavian-Tudorel¹, Gulya Aurelian³, Socea Bogdan¹, Bratu Ovidiu Gabriel¹⁴

¹ University of Medicine and Pharmacy “Carol Davilla”, Bucharest,
² University of Bucharest,
³ Moldova State University,
⁴ “Dr. Carol Davila” Central Military University Emergency Hospital

Disponibil în IBN: 13 decembrie 2018

Rezumat

New copper(II), manganese(II), cobalt(II), nickel(II) and palladium(II) complexes, [Cu(L)(X)(H₂O)] [X= OAc^- (1), Cl^- (3), ClO₄ ^- (4)], [M(L)₂(H₂O)₂] [M= Cu²⁺(2), Mn²⁺(5)], [M(L)(OAc)(H₂O)] [M= Co²⁺(6), Pd²⁺(8)], [Ni(L)(OAc)] (7) were synthesized with 2-(5H-dibenzo [a,d][7] annulen-5-ylacetyl)-N-(4-chlorophenyl) hydrazinecarbothioamide (HL). All the metal complexes have been characterized by different physico-chemical techniques like molar conductivity, magnetic susceptibility measurements, electronic and infrared spectral studies, elemental and thermal analysis. The toxicity of newly synthesized compounds was evaluated using the Daphnia magna bioassay.

Cuvinte-cheie
Cobalt(II), Copper(II), Hydrazinecarbothioamide, Manganese(II), Nickel(II) and palladium(II) complexes, Spectral studies, toxicity

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<title xml:lang='en'>Synthesis, characterization and toxicity evaluation of Cu(II), Mn(II), Co(II), Ni(II), Pd(II) complexes with ligand derived from hydrazinecarbothioamide</title>
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<publisher>Instrumentul Bibliometric National</publisher>
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<subject>Cobalt(II)</subject>
<subject>Copper(II)</subject>
<subject>Hydrazinecarbothioamide</subject>
<subject>Manganese(II)</subject>
<subject>Nickel(II) and palladium(II) complexes</subject>
<subject>Spectral studies</subject>
<subject>toxicity</subject>
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