Hexanuclear Fe(III) wheels functionalized by amino-acetonitrile derivatives

Kravtsov Victor; Malaestean Yurii; Styngach Evgenia; Duka Gh.; Makaev Fliur; Van Leusen Jan; Kogerler Paul; Hauser J; Kramer Karl W; Decurtins Silvio; Liu Shi-Xia; Ghosh Ashta; Garcia Yann; Baca Svetlana

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2018-08-07 14:10

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KRAVTSOV, Victor, MALAESTEAN, Yurii, STYNGACH, Evgenia, DUKA, Gh., MAKAEV, Fliur, VAN LEUSEN, Jan, KOGERLER, Paul, HAUSER, J, KRAMER, Karl W, DECURTINS, Silvio, LIU, Shi-Xia, GHOSH, Ashta, GARCIA, Yann, BACA, Svetlana. Hexanuclear Fe(III) wheels functionalized by amino-acetonitrile derivatives. In: Solid State Sciences, 2018, vol. 78, pp. 156-162. ISSN 1293-2558. DOI: https://doi.org/10.1016/j.solidstatesciences.2018.02.015

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Solid State Sciences

Volumul 78 / 2018 / ISSN 1293-2558 /ISSNe 1873-3085

Hexanuclear Fe(III) wheels functionalized by amino-acetonitrile derivatives

DOI:https://doi.org/10.1016/j.solidstatesciences.2018.02.015

Pag. 156-162

Kravtsov Victor¹, Malaestean Yurii¹, Styngach Evgenia², Duka Gh.², Makaev Fliur², Van Leusen Jan³, Kogerler Paul³, Hauser J⁴, Kramer Karl W⁴, Decurtins Silvio⁴, Liu Shi-Xia⁴, Ghosh Ashta⁵, Garcia Yann⁵, Baca Svetlana¹

¹ Institute of Applied Physics, Academy of Sciences of Moldova,
² Institute of Chemistry of the Academy of Sciences of Moldova,
³ RWTH Aachen University,
⁴ University of Bern,
⁵ Universitatea catolică din Louvain

Disponibil în IBN: 7 mai 2018

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Three new hexanuclear Fe(III) coordination wheels [Fe₆Cl₆(L1)₆]·5(MeCN) (1), [Na_0.5Fe₆Cl₆(L1)₆](N₃)_0.5·4.5(MeCN) (2), and [Fe₆Cl₆(L2)₆]·2(MeCN) (3) have been synthesized with new prepared amino-acetonitrile derivatives 2-[bis(2-hydroxyethyl)amino]acetonitrile hydrochloride (H₂L1) and 3-[bis(2-hydroxyethyl)amino]propanenitrile hydrochloride (H₂L2). They were structurally characterized by single-crystal X-ray diffraction. Mößbauer spectroscopy and magnetic susceptibility measurements indicate dominant antiferromagnetic behavior between the Fe(III) centers.

Cuvinte-cheie
N, X-ray diffraction, IronMagnetic properties, Mößbauer spectroscopy, O-ligands

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<title xml:lang='en'>Hexanuclear Fe(III) wheels functionalized by amino-acetonitrile derivatives</title>
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<description xml:lang='en' descriptionType='Abstract'><p>Three new hexanuclear Fe(III) coordination wheels [Fe<sub>6</sub>Cl<sub>6</sub>(L1)<sub>6</sub>]&middot;5(MeCN) (1), [Na<sub>0.5</sub>Fe<sub>6</sub>Cl<sub>6</sub>(L1)<sub>6</sub>](N<sub>3</sub>)<sub>0.5</sub>&middot;4.5(MeCN) (2), and [Fe<sub>6</sub>Cl<sub>6</sub>(L2)<sub>6</sub>]&middot;2(MeCN) (3) have been synthesized with new prepared amino-acetonitrile derivatives 2-[bis(2-hydroxyethyl)amino]acetonitrile hydrochloride (H<sub>2</sub>L1) and 3-[bis(2-hydroxyethyl)amino]propanenitrile hydrochloride (H<sub>2</sub>L2). They were structurally characterized by single-crystal X-ray diffraction. M&ouml;&szlig;bauer spectroscopy and magnetic susceptibility measurements indicate dominant antiferromagnetic behavior between the Fe(III) centers.</p></description>
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