<?xml version='1.0' encoding='utf-8'?>
<resource xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xmlns='http://datacite.org/schema/kernel-3' xsi:schemaLocation='http://datacite.org/schema/kernel-3 http://schema.datacite.org/meta/kernel-3/metadata.xsd'>
<creators>
<creator>
<creatorName>Lozan, V.I.</creatorName>
<affiliation>Institutul de Chimie al AŞM, Moldova, Republica</affiliation>
</creator>
</creators>
<titles>
<title xml:lang='en'>Dinuclear complexes as building blocks for
tetra-nuclear macrocyclic complexes with dithiolate macrocyclic ligand
</title>
</titles>
<publisher>Instrumentul Bibliometric National</publisher>
<publicationYear>2013</publicationYear>
<relatedIdentifier relatedIdentifierType='ISSN' relationType='IsPartOf'>1857-1727</relatedIdentifier>
<subjects>
<subject>coordination chemistry</subject>
<subject>amino-thiophenolate ligands</subject>
<subject>di- and tetranuclear complexes</subject>
<subject>ferrocene and naphthalene diimide derivatives</subject>
<subject>polynuclear complexes</subject>
</subjects>
<dates>
<date dateType='Issued'>2013-02-01</date>
</dates>
<resourceType resourceTypeGeneral='Text'>Journal article</resourceType>
<descriptions>
<description xml:lang='en' descriptionType='Abstract'>A series of novel tri-, tetra- and pentanuclear complexes composed of dinuclear LM2 units (M=Co, Ni,Zn; L=24-membered macrocyclic hexaaza-dithiophenolate ligand) and ferrocene-carboxylate ([CpFeC5H4CO2]ˉ),1,1’-ferro-cenedicarboxylate([Fe(C5H4-CO2)2]2ˉ), acetylenedicarboxylate, terephthalate, isophthalate, and naphthalene diimide dicar-boxylate groups is reported. The complexes have been synthesized and characterised by UV/Vis-,
IR-spectroscopy, and X-ray crystallography. Each dicarboxylate dianion acts as a quadridentate bridging ligand linking two bioctahedral LM2 units via μ1,3-bridging carboxylate functions to generate discrete dications with a central LM2(O2C-R-CO2)M2L core.</description>
</descriptions>
<formats>
<format>application/pdf</format>
</formats>
</resource>