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SM ISO690:2012 LOZAN, Vasile. Dinuclear complexes as building blocks for
tetra-nuclear macrocyclic complexes with dithiolate macrocyclic ligand
. In: Chemistry Journal of Moldova, 2013, nr. 1(8), pp. 58-77. ISSN 1857-1727. |
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Chemistry Journal of Moldova | ||||||
Numărul 1(8) / 2013 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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Pag. 58-77 | ||||||
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Rezumat | ||||||
A series of novel tri-, tetra- and pentanuclear complexes composed of dinuclear LM2 units (M=Co, Ni,Zn; L=24-membered macrocyclic hexaaza-dithiophenolate ligand) and ferrocene-carboxylate ([CpFeC5H4CO2]ˉ),1,1’-ferro-cenedicarboxylate([Fe(C5H4-CO2)2]2ˉ), acetylenedicarboxylate, terephthalate, isophthalate, and naphthalene diimide dicar-boxylate groups is reported. The complexes have been synthesized and characterised by UV/Vis-,
IR-spectroscopy, and X-ray crystallography. Each dicarboxylate dianion acts as a quadridentate bridging ligand linking two bioctahedral LM2 units via μ1,3-bridging carboxylate functions to generate discrete dications with a central LM2(O2C-R-CO2)M2L core. |
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Cuvinte-cheie coordination chemistry, polynuclear complexes, amino-thiophenolate ligands, di- and tetranuclear complexes, ferrocene and naphthalene diimide derivatives |
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