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<oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'>
<dc:creator>Lozan, V.I.</dc:creator>
<dc:date>2013-02-01</dc:date>
<dc:description xml:lang='en'>A series of novel tri-, tetra- and pentanuclear complexes composed of dinuclear LM2 units (M=Co, Ni,Zn; L=24-membered macrocyclic hexaaza-dithiophenolate ligand) and ferrocene-carboxylate ([CpFeC5H4CO2]ˉ),1,1’-ferro-cenedicarboxylate([Fe(C5H4-CO2)2]2ˉ), acetylenedicarboxylate, terephthalate, isophthalate, and naphthalene diimide dicar-boxylate groups is reported. The complexes have been synthesized and characterised by UV/Vis-,
IR-spectroscopy, and X-ray crystallography. Each dicarboxylate dianion acts as a quadridentate bridging ligand linking two bioctahedral LM2 units via μ1,3-bridging carboxylate functions to generate discrete dications with a central LM2(O2C-R-CO2)M2L core.</dc:description>
<dc:source>Chemistry Journal of Moldova 8 (1) 58-77</dc:source>
<dc:subject>coordination chemistry</dc:subject>
<dc:subject>amino-thiophenolate ligands</dc:subject>
<dc:subject>di- and tetranuclear complexes</dc:subject>
<dc:subject>ferrocene and naphthalene diimide derivatives</dc:subject>
<dc:subject>polynuclear complexes</dc:subject>
<dc:title>Dinuclear complexes as building blocks for
tetra-nuclear macrocyclic complexes with dithiolate macrocyclic ligand
</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
</oai_dc:dc>