Photoluminescence of composites based on Eu3+/TTFA and polymer SBMA
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YOVU, M., ANDRIESH, Andrei, BUZURNIUC, Svetlana, VERLAN, Victor, CARAMAN, Mihail, ZUBAREVA, Vera. Photoluminescence of composites based on Eu3+/TTFA and polymer SBMA. In: Journal of Optoelectronics and Advanced Materials, 2007, vol. 9, pp. 3265-3267. ISSN 1454-4164.
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Journal of Optoelectronics and Advanced Materials
Volumul 9 / 2007 / ISSN 1454-4164

Photoluminescence of composites based on Eu3+/TTFA and polymer SBMA


Pag. 3265-3267

Yovu M.1, Andriesh Andrei1, Buzurniuc Svetlana1, Verlan Victor1, Caraman Mihail2, Zubareva Vera3
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 Moldova State University,
3 Institute of Chemistry of the Academy of Sciences of Moldova
 
 
Disponibil în IBN: 26 februarie 2024


Rezumat

New composite material on the base of thienyltrifluoroacetonate (TTA) coordinated with trivalent europium ions without and with polymer from styrene and butylmethacrilate (1:1) (SBMA) was prepared. The visible emission spectra of the composites at room temperature and at T=78 K when excited with Ar-laser (λ=0.33 μm). For the Eu3+/TTA composite material some sharp emission bands located at 5795, 590, 596, 615 and 620 nm at T=300 K, and at 580, 593, 595, 614, 618, 651, 656, 694, 698, and 700 nm at T=78 K were detected. The emission bands centered at 580, 590, 615, 651, and 700 nm can be attributed to the spin forbidden f-f transitions 5D0 → 7Fi (i = 0,1,2,3 and 4), respectively.

Cuvinte-cheie
composites, Fluorescence, optical absorption, polymer, Rare-earth ion, thin film