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 SM ISO690:2012GERASIMENKO, Andrey, DAVIDOVICH, Ruven, BULIMESTRU, Ion, GULYA, Aurelian. Bis(μ-salicylaldehyde semicarbazonato)-bis[formatocopper(II)]. In: Acta Crystallographica Section E: Structure Reports Online, 2005, vol. 61, pp. 1816-1817. ISSN 1600-5368. DOI: https://doi.org/10.1107/S1600536805025845 |
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 Acta Crystallographica Section E: Structure Reports Online |
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| Volumul 61 / 2005 / ISSN 1600-5368 | ||||||
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| DOI:https://doi.org/10.1107/S1600536805025845 | ||||||
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The salicylaldehyde semicarbazonate anion O,N,O-chelates to the Cu atom in the title compound, bis[μ-2-(semicarbazonomethyl)phenolato]- 1κ3O3,N1,O:2κO;1κO: 2κ3O3,N1,O-bis-[(formato-κO) copper(II)] [Cu2(C8H8N3O 2)2(CHO2)2], the N and O atoms occupying three sites of the square-planar environment around it. The fourth site is occupied by the negatively charged O atom of the formate anion. Two molecules are bridged through the phenoxy O atom across a center of symmetry to give a dinuclear compound, so that the Cu atom exists in a square-pyramidal geometry [Cu←Ophenoxy = 2.546 (1) Å in the apical position]. Hydrogen bonds link the dinuclear molecules into a three-dimensional network architecture. |
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| Cuvinte-cheie complex, 2-acetylpyridine, Schiff bases |
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Dublin Core Export
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Gerasimenko, A.V.</dc:creator> <dc:creator>Davidovich, R.L.</dc:creator> <dc:creator>Bulimestru, I.</dc:creator> <dc:creator>Гуля, ..</dc:creator> <dc:creator>Гуля, ..</dc:creator> <dc:date>2005-09-01</dc:date> <dc:description xml:lang='en'><p>The salicylaldehyde semicarbazonate anion O,N,O-chelates to the Cu atom in the title compound, bis[μ-2-(semicarbazonomethyl)phenolato]- 1κ<sup>3</sup>O<sup>3</sup>,N<sup>1</sup>,O:2κO;1κO: 2κ<sup>3</sup>O<sup>3</sup>,N<sup>1</sup>,O-bis-[(formato-κO) copper(II)] [Cu<sub>2</sub>(C<sub>8</sub>H<sub>8</sub>N<sub>3</sub>O <sub>2</sub>)<sub>2</sub>(CHO<sub>2</sub>)<sub>2</sub>], the N and O atoms occupying three sites of the square-planar environment around it. The fourth site is occupied by the negatively charged O atom of the formate anion. Two molecules are bridged through the phenoxy O atom across a center of symmetry to give a dinuclear compound, so that the Cu atom exists in a square-pyramidal geometry [Cu←O<sub>phenoxy</sub> = 2.546 (1) Å in the apical position]. Hydrogen bonds link the dinuclear molecules into a three-dimensional network architecture.</p></dc:description> <dc:identifier>10.1107/S1600536805025845</dc:identifier> <dc:source>Acta Crystallographica Section E: Structure Reports Online () 1816-1817</dc:source> <dc:subject>complex</dc:subject> <dc:subject>2-acetylpyridine</dc:subject> <dc:subject>Schiff bases</dc:subject> <dc:title>Bis(μ-salicylaldehyde semicarbazonato)-bis[formatocopper(II)]</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>
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