Spectroscopic study of amorphous As2Se3:Sn x and (As2S1.5Se1.5) 1-x:Snx thin films
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IASENIUC, Oxana, HAREA, Diana, YOVU, M., KOLOMEYKO, Eduard, HAREA, Evghenii, COJOCARU, Ion, SHEPEL, Diana, MESHALKIN, Alexei. Spectroscopic study of amorphous As2Se3:Sn x and (As2S1.5Se1.5) 1-x:Snx thin films. In: Proceedings of SPIE - The International Society for Optical Engineering, Ed. 6, 23-26 august 2012, Constanta. Bellingham, Washington: SPIE, 2012, Ediţia 6, Vol.8411, pp. 1-9. ISBN 9780819490896. ISSN 0277-786X. DOI: https://doi.org/10.1117/12.956493
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Proceedings of SPIE - The International Society for Optical Engineering
Ediţia 6, Vol.8411, 2012
Conferința "Advanced Topics in Optoelectronics, Microelectronics, and Nanotechnologies"
6, Constanta, Romania, 23-26 august 2012

Spectroscopic study of amorphous As2Se3:Sn x and (As2S1.5Se1.5) 1-x:Snx thin films

DOI:https://doi.org/10.1117/12.956493

Pag. 1-9

Iaseniuc Oxana1, Harea Diana1, Yovu M.1, Kolomeyko Eduard1, Harea Evghenii1, Cojocaru Ion1, Shepel Diana12, Meshalkin Alexei1
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 Institute of Chemistry of the Academy of Sciences of Moldova
 
Proiecte:
 
Disponibil în IBN: 29 noiembrie 2023


Rezumat

The transmission spectra of bulk and thin films of (As 2 S 1.5 Se 1.5) 1-x:Sn x in the visible and near infrared (IR) regions were investigated. Doping of As 2 S 1.5 Se 1.5 chalcogenide glass with tin impurities essentially reduce the absorption bands of SH (Se-H) and H 2 O located at ν = 5190 cm -1 and ν = 3617 cm -1, respectively. The amorphous As 2 Se 3:Sn x and (As 2 S 1.5 Se 1.5) 1-x:Sn x thin films exhibit photoinduced effects under the light irradiation with photon energy above the optical band gap (hν≥E g), that make its perspective materials for registration of optical and holographic information. The modification of optical parameters (optical band gap E g, absorption coefficient α, refractive index n) under light irradiation and heat treatment of the amorphous thin films with different amount of Sn was studied. The shift of the absorption edge after light exposure to lower energy region was observed, i.e. the effect of photodarkening take place. The dispersions curves n=f(λ) show a modification of the refractive index n under light exposure. For the glass composition (As 2 S 1.5 Se 1.5) 0.96:Sn 0.04 the change of the optical band gap Eg opt under light exposure was determined from 1.92±0.02 eV to 1.86±0.02 eV. The similar calculations of the optical constants were done for the amorphous films of glass compositions x=0.03 and x=0.05. The relaxation of photodarkening in amorphous As 2 Se 3:Sn x and (As 2 S 1.5 Se 1.5) 1-x:Sn x thin films, which is described by the stretch exponential function T(t)/T(0) = A 0 +Aexp[-(t-t 0)/τ] (1-α) also wasinvestigated. The experimental results are interpreted in framework of the model of molecular structure of chalcogenide glasses doped with tin impurities. 

Cuvinte-cheie
Amorphous films, chalcogenide glasses, optical absorption, photodarkening, refractive index