Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
124 5 |
Ultima descărcare din IBN: 2023-10-30 10:03 |
SM ISO690:2012 GULYA, Aurelian, CHUMAKOV, Yurii, GRAUR, Vasilii О., TSAPKOV, Victor I.. Coordination compounds of copper(II) with substituted 3-{[(2-hydroxyphenyl) methylidene]amino}propane-1,2-diols. In: Russian Journal of General Chemistry, 2013, vol. 83, pp. 1666-1672. ISSN 1070-3632. DOI: https://doi.org/10.1134/S1070363213090077 |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
Russian Journal of General Chemistry | ||||||
Volumul 83 / 2013 / ISSN 1070-3632 /ISSNe 1608-3350 | ||||||
|
||||||
DOI:https://doi.org/10.1134/S1070363213090077 | ||||||
Pag. 1666-1672 | ||||||
|
||||||
Descarcă PDF | ||||||
Rezumat | ||||||
3-{[(2-Hydroxyphenyl)methylidene]amino}propane-1,2-diol, its 5-chloro-,5-bromo-, 5-nitro-, 3-methoxy derivatives, and 3-{[(2-hydroxynaphthyl- 1)methylidene]amino}propane-1,2-diol react with hydrates of copper(II) chloride, bromide and nitrate in ethanol to form coordination compounds Cu(L)X·nH2O. Template condensation reaction between 3-aminopropane-1,2-diol and 2,3-, 2,4- or 2,5-dihydroxybenzaldehyde in the presence of copper(II) nitrate trihydrate results in similar compounds Cu(L)NO3·nH2O. Structure of some of the condensation products was identified by X-ray analysis. Thermolysis of the substances obtained occurs through the dehydration step (70-90 C) and complete thermal decomposition (290-560 C). |
||||||
|