Synthesis of 1,2,3-Triazole-Substituted 3,7,7-Trimethylbicyclo[4.1.0]Heptanols Based on (+)-3-Carene
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CURLAT, Serghei, MAKAEV, Fliur. Synthesis of 1,2,3-Triazole-Substituted 3,7,7-Trimethylbicyclo[4.1.0]Heptanols Based on (+)-3-Carene. In: Chemistry of Natural Compounds, 2021, nr. 1(57), pp. 733-740. ISSN 0009-3130.
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Chemistry of Natural Compounds
Numărul 1(57) / 2021 / ISSN 0009-3130

Synthesis of 1,2,3-Triazole-Substituted 3,7,7-Trimethylbicyclo[4.1.0]Heptanols Based on (+)-3-Carene


Pag. 733-740

Curlat Serghei, Makaev Fliur
 
Institute of Chemistry
 
 
Disponibil în IBN: 12 noiembrie 2021


Rezumat

Regioisomeric 3,7,7-trimethylbicyclo[4.1.0]heptanols and their acetoacetates with substituted 1,2,3-triazole fragments were synthesized via azide–alkyne cycloaddition reactions of azidocaranols and mono-substituted acetylenes. A one-pot synthesis of symmetric and asymmetric esters of carane-type 2,6-dimethylpyridine-3,5-dicarboxylic acid was proposed.

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<dc:creator>Curlat, S.N.</dc:creator>
<dc:creator>Macaev, F.Z.</dc:creator>
<dc:date>2021-01-28</dc:date>
<dc:description xml:lang='en'><p>Regioisomeric 3,7,7-trimethylbicyclo[4.1.0]heptanols and their acetoacetates with substituted 1,2,3-triazole fragments were synthesized via azide&ndash;alkyne cycloaddition reactions of azidocaranols and mono-substituted acetylenes. A one-pot synthesis of symmetric and asymmetric esters of carane-type 2,6-dimethylpyridine-3,5-dicarboxylic acid was proposed.</p></dc:description>
<dc:source>Chemistry of Natural Compounds 57 (1) 733-740</dc:source>
<dc:title>Synthesis of 1,2,3-Triazole-Substituted 3,7,7-Trimethylbicyclo[4.1.0]Heptanols Based on (+)-3-Carene</dc:title>
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