Synthesis of 1,2,3-Triazole-Substituted 3,7,7-Trimethylbicyclo[4.1.0]Heptanols Based on (+)-3-Carene

Curlat Serghei; Makaev Fliur

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CURLAT, Serghei, MAKAEV, Fliur. Synthesis of 1,2,3-Triazole-Substituted 3,7,7-Trimethylbicyclo[4.1.0]Heptanols Based on (+)-3-Carene. In: Chemistry of Natural Compounds, 2021, nr. 1(57), pp. 733-740. ISSN 0009-3130.

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Chemistry of Natural Compounds

Numărul 1(57) / 2021 / ISSN 0009-3130

Synthesis of 1,2,3-Triazole-Substituted 3,7,7-Trimethylbicyclo[4.1.0]Heptanols Based on (+)-3-Carene

Pag. 733-740

Curlat Serghei, Makaev Fliur

Institute of Chemistry

Disponibil în IBN: 12 noiembrie 2021

Rezumat

Regioisomeric 3,7,7-trimethylbicyclo[4.1.0]heptanols and their acetoacetates with substituted 1,2,3-triazole fragments were synthesized via azide–alkyne cycloaddition reactions of azidocaranols and mono-substituted acetylenes. A one-pot synthesis of symmetric and asymmetric esters of carane-type 2,6-dimethylpyridine-3,5-dicarboxylic acid was proposed.

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