| Conţinutul numărului revistei |
| Articolul precedent |
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 SM ISO690:2012CROITOR, Lilia, COROPCEANU, Eduard, PETUHOV, Oleg, KRAMER, Karl W, BACA, Svetlana, LIU, Shi-Xia, DECURTINS, Silvio, FONARI, Marina. A one-dimensional coordination polymer based on Cu3-oximato metallacrowns bridged by benzene-1,4-dicarboxylato ligands: Structure and magnetic properties. In: Dalton Transactions, 2015, vol. 44, nr. 17, pp. 7896-7902. ISSN 1477-9226. DOI: https://doi.org/10.1039/c5dt00533g |
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  Dalton Transactions |
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| Volumul 44, Numărul 17 / 2015 / ISSN 1477-9226 /ISSNe 1477-9234 | ||||||
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| DOI:https://doi.org/10.1039/c5dt00533g | ||||||
| Pag. 7896-7902 | ||||||
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| Rezumat | ||||||
A one-dimensional linear coordination polymer {[Cu3(μ3-OH)(2-pyao)3(bdc)]·6(H2O)}n (1) composed of trinuclear [Cu3(μ3-OH)(2-pyao)3]2+ metallacrown cores bridged by bis-carboxylato linkers has been obtained by treatment of copper(ii) fluoride with pyridine-2-aldoxime (2-pyaoH) ligand and benzene-1,4-dicarboxylic acid (H2bdc). Magnetic susceptibility measurements show strong antiferromagnetic interactions between Cu(ii) centers within the trinuclear metallacrown core with J = -430 cm-1. |
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| Cuvinte-cheie Aldoximes, Antiferro-magnetic interactions, Carboxylato, coordination polymers, Magnetic susceptibility measurements, One-dimensional coordination polymer, Pyridine-2, Trinuclear |
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