<?xml version='1.0' encoding='utf-8'?>
<oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'>
<dc:creator>Cuzan, O.I.</dc:creator>
<dc:date>2017</dc:date>
<dc:description xml:lang='en'><p>The novel N-(methylene-2-pyridine)-N,N-bis(diethoxyphosphorylmethyl)amine ligand (L) was obtained through a double Kabachnik-Fields reaction, starting from 2-aminomethyl pyridine (2-picolylamine). In the perspective of developing new catalysts for clean water mediated reactions, a new palladium(II) coordination compound [Pd(L)2Cl2] based on the L ligand, has been synthetized and comprehensively characterized by spectroscopic methods (1H NMR, UV-Vis), ESI mass spectrometry and X-ray crystallography. Figure 1. Scheme of the synthesis of the complex [Pd(L)2Cl2] from ligand L. The [Pd (L)2Cl2] complex crystallizes in the triclinic centrosymmetric space group P-1. The palladium has a square planar coordination sphere provided by two nitrogen and two chlorine atoms in a trans arrangement. The pyridinic rings are situated perpendicular to the plane formed by the central metal and its coordination sphere.</p></dc:description>
<dc:source>Ecological and environmental chemistry  (Ediția 6) 227-227</dc:source>
<dc:title>Synthesis and characterisation of a new palladium (II) coordination compound starting from a novel phosphonate ligand</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
</oai_dc:dc>