<?xml version='1.0' encoding='utf-8'?>
<oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'>
<dc:creator>Coropceanu, E.B.</dc:creator>
<dc:creator>Meriacri, M.</dc:creator>
<dc:creator>Vitiu (Boldişor), A.A.</dc:creator>
<dc:creator>Bouroş, P.N.</dc:creator>
<dc:date>2014</dc:date>
<dc:description xml:lang='en'><p>Aiming to create coordinative polymers of different dimensions there have been assembled two new coordinative polymers of the cobalt(II) with dicarboxylic acids and 4-pyridylamidoxime with the following fo1mulas: [Co(adi)(4-pyamo)2]n (1) and {[Co(tph)(4-pyamo)2]-2dmf.2H20}n (2) (H2adi - adipic acid, H2tph - terephthalic acid; 4-pyamo - 4-pyridylamidoxime). The X-ray study has established that both compounds c1ystallize in the triclinic P-1 space group. Each metal atom in both compounds have the octahedral coordination polyhedron, consisting of 04N2 donor atoms set going from two bideprotonated adipato anions and two neutral 4-pyamo ligands in 1, and two bideprotonated terephthalate and two neutral 4-pyamo ligands and two coordinated water molecules in 2. The 4-pyamo molecule coordinates to the Co(II) center in monodentate mode via the pyridine N-binding site, while the adipato anion coordinates in bis-chelating bridging mode and terephthalate anion in bridging bis-monodentate mode. Such coordinating mode of adipic acid dete1minated in 1, was established in some of the compounds with dicarboxylic acids and 4-pyridilaldoxime [1]. The bridging adi anions are responsible for ID z</p></dc:description>
<dc:source>Materials Science and Condensed Matter Physics (Editia 7) 198-198</dc:source>
<dc:title>Self-assembly of Co(II) coordination polymers with dicarboxylic acids and 4-pyridylamidoxime</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
</oai_dc:dc>