Synthesis and study of nickel-containing hydrogenase model compound
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STRĂISTARI, Tatiana, TURTA, Constantin, REGLIER, Marius, ARSENE, Ion, GORINCHOY, Natalia. Synthesis and study of nickel-containing hydrogenase model compound. In: The International Conference dedicated to the 55th anniversary from the foundation of the Institute of Chemistry of the Academy of Sciences of Moldova, 28-30 mai 2014, Chișinău. Chișinău, Republica Moldova: Institutul de Chimie al AȘM, 2014, p. 122.
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The International Conference dedicated to the 55th anniversary from the foundation of the Institute of Chemistry of the Academy of Sciences of Moldova 2014
Conferința "The International Conference dedicated to the 55th anniversary from the foundation of the Institute of Chemistry of the Academy of Sciences of Moldova"
Chișinău, Moldova, 28-30 mai 2014

Synthesis and study of nickel-containing hydrogenase model compound

Pag. 122-122

Străistari Tatiana1, Turta Constantin1, Reglier Marius2, Arsene Ion1, Gorinchoy Natalia1
 
1 Institute of Chemistry of the Academy of Sciences of Moldova,
2 Université d’Aix-Marseille
 
Proiecte:
 
Disponibil în IBN: 24 ianuarie 2019
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Of particular interest is the synthesis and study of new coordination compounds of nickel as active centers of Hydrogenazes[1-2]. In order to mimic the active centres of the Hydrogenazes, a Ni complex bis (4 - (p-metoxifenil)thiosemicarbazone)-2,3-butane was synthesized (Fig.1). According to the UV-Vis spectra of ligand and nickel complex the maximum of absorption peak is transferred in the red part indicating the decrease of the HOMO-LUMO energy gap (Fig. 2, and 3). Calculated (TDDFT, GAUSSIAN09 [3]) UV-Vis Fig.1. Structure of [NiL2](DMSO) spectra show a rather good agreement with the experimental ones. They can be classified as manly the ligand-ligand transitions. The compound shows electrocatalytic proton reduction in the cyclic voltammetry experiment with value of TOF ≥ 200 s-1.

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