Synthesis and crystal structure of bis(citrato) germanate and stannate with tris (phenanthroline) nickel(II) cation

Martsinko Elena; Seifullina Inna; Chebanenko Elena; Pirozhok Olha; Dyakonenko Viktoriya; Shishkina Svitlana

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2023-08-16 21:35

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54+66 (9)

Chimie. Cristalografie. Mineralogie (2025)

Tehnologie chimică. Industrii chimice și înrudite (1503)

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MARTSINKO, Elena, SEIFULLINA, Inna, CHEBANENKO, Elena, PIROZHOK, Olha, DYAKONENKO, Viktoriya, SHISHKINA, Svitlana. Synthesis and crystal structure of bis(citrato) germanate and stannate with tris (phenanthroline) nickel(II) cation. In: Chemistry Journal of Moldova, 2018, nr. 2(13), pp. 56-62. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2018.513

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Chemistry Journal of Moldova

Numărul 2(13) / 2018 / ISSN 1857-1727 /ISSNe 2345-1688

Synthesis and crystal structure of bis(citrato) germanate and stannate with tris (phenanthroline) nickel(II) cation

DOI:https://doi.org/10.19261/cjm.2018.513

CZU: 54+66

Pag. 56-62

Martsinko Elena¹, Seifullina Inna¹, Chebanenko Elena¹, Pirozhok Olha¹, Dyakonenko Viktoriya², Shishkina Svitlana²³

¹ Odesa I.I.Mechnikov National University,
² National Academy of Science of Ukraine,
³ V.N.Karazin Kharkiv Natsonal University

Disponibil în IBN: 24 decembrie 2018

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The new complexes [Ni(phen)3][Ge(HCit)2]·2H2O (1), [Ni(phen)3][Sn(HCit)2]·3H2O (2) (where phen is 1,10-phenanthroline, H4Cit is citric acid) were synthesized. The identity, composition, and thermal stability of the complexes were established by elemental analysis, thermogravimetry, and IR spectroscopy. According to the data of X-ray diffraction, the bis(citrate)germanate/bis(citrate)stannate [Ge/Sn(HCit)2]2- is the anion, while [Ni(phen)3]2+ is the cation in the studied complexes. The coordination polyhedrons of Ge, Sn and Ni atoms are octahedral and are formed by three pairs of oxygen atoms of different types of two HCit-3 ligands or by three 1,10-phenanthroline molecules.

Cuvinte-cheie
citric acid, 10-phenanthroline, germanium(IV), tin(IV), nickel(II) complex., 1

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