Synthesis of pinonic acid new derivatives
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2022-11-03 00:39
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GUDIMA, Alexandru, VLAD, Ludmila, MACAEV, Fliur. Synthesis of pinonic acid new derivatives . In: Chemistry Journal of Moldova, 2008, nr. 2(3), pp. 122-123. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 2(3) / 2008 / ISSN 1857-1727 /ISSNe 2345-1688

Synthesis of pinonic acid new derivatives

Pag. 122-123

Gudima Alexandru, Vlad Ludmila, Macaev Fliur
 
Institutul de Chimie al AŞM
 
 
Disponibil în IBN: 13 decembrie 2013


Rezumat

The method for synthetising new derivatives of the pinonic acid using, at the key step, the reaction of condensation with epichlorohydrin, has been elaborated. It has been shown that, in the presence of catalytic amount of tetrabutylammonium chloride, the reaction is directed towards the formation of etherchlorohydrin, which, later on, is easily transformed into epoxides as well as chloromethyldiketones with good overall yield.

Cuvinte-cheie
pinonic acid, chlorohydrin,

epoxide