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 SM ISO690:2012ROMAN, Marianna, DECURTINS, Silvio, LIU, Shi-Xia, KLOKISHNER, Sophia I.. Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe–Co Clusters. In: European Journal of Inorganic Chemistry, 2016, nr. 34(2016), pp. 1324-1331. ISSN 1434-1948. DOI: https://doi.org/10.1002/ejic.201600782 |
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  European Journal of Inorganic Chemistry |
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| Numărul 34(2016) / 2016 / ISSN 1434-1948 /ISSNe 1099-0682 | ||||||
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| DOI:https://doi.org/10.1002/ejic.201600782 | ||||||
| Pag. 1324-1331 | ||||||
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We present a new microscopic approach for the description of the effects of an external direct current (dc) electric field on the magnetic, polarizability, and spectroscopic characteristics of molecular crystals containing cyanide-bridged Fe–Co clusters as structural units. In addition to the interaction with the electric field, the model allows for metal–metal electron transfer, intracluster magnetic exchange, and long-range electron-deformational interactions, which are taken into account within the mean-field approach. The external electric field gives a unique possibility to manipulate the polarizability, magnetic, and spectroscopic characteristics of cyanide-bridged Fe–Co clusters. |
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| Cuvinte-cheie cobalt, Electron transfer, iron, magnetic properties, Moessbauer spectroscopy, Polarizability |
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<meta name="citation_title" content="Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe–Co Clusters"> <meta name="citation_author" content="Roman Marianna"> <meta name="citation_author" content="Decurtins Silvio"> <meta name="citation_author" content="Liu Shi-Xia"> <meta name="citation_author" content="Klokishner Sophia I."> <meta name="citation_publication_date" content="2016/11/03"> <meta name="citation_journal_title" content="European Journal of Inorganic Chemistry"> <meta name="citation_volume" content="2016"> <meta name="citation_issue" content="34"> <meta name="citation_firstpage" content="1324"> <meta name="citation_lastpage" content="1331"> <meta name="citation_pdf_url" content="http://onlinelibrary.wiley.com/doi/10.1002/ejic.201600782/abstract;jsessionid=17FCF7C1C351B78C967AB1E4113749C4.f02t01">
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