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![]() , , DECURTINS, Silvio, LIU, Shi-Xia, KLOKISHNER, Sophia I.. Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe–Co Clusters. In: European Journal of Inorganic Chemistry, 2016, nr. 34(2016), pp. 1324-1331. ISSN 1434-1948. DOI: https://doi.org/10.1002/ejic.201600782 |
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European Journal of Inorganic Chemistry | ||||||
Numărul 34(2016) / 2016 / ISSN 1434-1948 /ISSNe 1099-0682 | ||||||
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DOI:https://doi.org/10.1002/ejic.201600782 | ||||||
Pag. 1324-1331 | ||||||
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Rezumat | ||||||
We present a new microscopic approach for the description of the effects of an external direct current (dc) electric field on the magnetic, polarizability, and spectroscopic characteristics of molecular crystals containing cyanide-bridged Fe–Co clusters as structural units. In addition to the interaction with the electric field, the model allows for metal–metal electron transfer, intracluster magnetic exchange, and long-range electron-deformational interactions, which are taken into account within the mean-field approach. The external electric field gives a unique possibility to manipulate the polarizability, magnetic, and spectroscopic characteristics of cyanide-bridged Fe–Co clusters. |
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Cuvinte-cheie cobalt, Electron transfer, iron, magnetic properties, Moessbauer spectroscopy, Polarizability |
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<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator></dc:creator> <dc:creator>Decurtins, S.</dc:creator> <dc:creator>Liu, S.</dc:creator> <dc:creator>Clochişner, S.I.</dc:creator> <dc:date>2016-11-03</dc:date> <dc:description xml:lang='en'><p>We present a new microscopic approach for the description of the effects of an external direct current (dc) electric field on the magnetic, polarizability, and spectroscopic characteristics of molecular crystals containing cyanide-bridged Fe–Co clusters as structural units. In addition to the interaction with the electric field, the model allows for metal–metal electron transfer, intracluster magnetic exchange, and long-range electron-deformational interactions, which are taken into account within the mean-field approach. The external electric field gives a unique possibility to manipulate the polarizability, magnetic, and spectroscopic characteristics of cyanide-bridged Fe–Co clusters.</p></dc:description> <dc:identifier>10.1002/ejic.201600782</dc:identifier> <dc:source>European Journal of Inorganic Chemistry 2016 (34) 1324-1331</dc:source> <dc:subject>cobalt</dc:subject> <dc:subject>Electron transfer</dc:subject> <dc:subject>iron</dc:subject> <dc:subject>magnetic properties</dc:subject> <dc:subject>Moessbauer spectroscopy</dc:subject> <dc:subject>Polarizability</dc:subject> <dc:title>Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe–Co Clusters</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>