Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe–Co Clusters
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, , DECURTINS, Silvio, LIU, Shi-Xia, KLOKISHNER, Sophia I.. Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe–Co Clusters. In: European Journal of Inorganic Chemistry, 2016, nr. 34(2016), pp. 1324-1331. ISSN 1434-1948. DOI: https://doi.org/10.1002/ejic.201600782
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European Journal of Inorganic Chemistry
Numărul 34(2016) / 2016 / ISSN 1434-1948 /ISSNe 1099-0682

Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe–Co Clusters

DOI:https://doi.org/10.1002/ejic.201600782

Pag. 1324-1331

1, Decurtins Silvio2, Liu Shi-Xia2, Klokishner Sophia I.1
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 University of Bern
 
 
Disponibil în IBN: 3 noiembrie 2017


Rezumat

We present a new microscopic approach for the description of the effects of an external direct current (dc) electric field on the magnetic, polarizability, and spectroscopic characteristics of molecular crystals containing cyanide-bridged Fe–Co clusters as structural units. In addition to the interaction with the electric field, the model allows for metal–metal electron transfer, intracluster magnetic exchange, and long-range electron-deformational interactions, which are taken into account within the mean-field approach. The external electric field gives a unique possibility to manipulate the polarizability, magnetic, and spectroscopic characteristics of cyanide-bridged Fe–Co clusters.

Cuvinte-cheie
cobalt, Electron transfer, iron, magnetic properties,

Moessbauer spectroscopy, Polarizability

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<dc:creator></dc:creator>
<dc:creator>Decurtins, S.</dc:creator>
<dc:creator>Liu, S.</dc:creator>
<dc:creator>Clochişner, S.I.</dc:creator>
<dc:date>2016-11-03</dc:date>
<dc:description xml:lang='en'><p>We present a new microscopic approach for the description of the effects of an external direct current (dc) electric field on the magnetic, polarizability, and spectroscopic characteristics of molecular crystals containing cyanide-bridged Fe&ndash;Co clusters as structural units. In addition to the interaction with the electric field, the model allows for metal&ndash;metal electron transfer, intracluster magnetic exchange, and long-range electron-deformational interactions, which are taken into account within the mean-field approach. The external electric field gives a unique possibility to manipulate the polarizability, magnetic, and spectroscopic characteristics of cyanide-bridged Fe&ndash;Co clusters.</p></dc:description>
<dc:identifier>10.1002/ejic.201600782</dc:identifier>
<dc:source>European Journal of Inorganic Chemistry 2016 (34) 1324-1331</dc:source>
<dc:subject>cobalt</dc:subject>
<dc:subject>Electron transfer</dc:subject>
<dc:subject>iron</dc:subject>
<dc:subject>magnetic properties</dc:subject>
<dc:subject>Moessbauer spectroscopy</dc:subject>
<dc:subject>Polarizability</dc:subject>
<dc:title>Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe&ndash;Co Clusters</dc:title>
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