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SM ISO690:2012 GUTSANU, Vasile, LISĂ, Gabriela Apreotesei, VIZIR, Constantin, TUDORACHI, Nita. Sorption and thermal properties of strongly basic cross-linked ionic polymer modified with Cr(III) compounds. In: Journal of Applied Polymer Science, 2015, vol. 132, pp. 1-10. ISSN 0021-8995. DOI: https://doi.org/10.1002/APP.41306 |
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Journal of Applied Polymer Science | ||||||
Volumul 132 / 2015 / ISSN 0021-8995 /ISSNe 1097-4628 | ||||||
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DOI:https://doi.org/10.1002/APP.41306 | ||||||
Pag. 1-10 | ||||||
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AV-17(Cr) material was prepared by modifying a commercial polymer AV-17 (initially bearing R4N+ functional groups) with Cr(III) compounds was investigated. Comparative isotherms characterizing the CrO42- and Cr2O72- ion sorption from solution with pH values of 3 and 8, respectively, at 19°C and 60°C, were obtained using the raw AV-17(Cl) and the modified AV-17(Cr) material. The sorption process on AV-17(Cr) takes place through the coordination of Cr(VI) ions with Cr(III) ions, while on AV-17(Cl) it is due to an ion exchange mechanism. The sorption isotherms obtained in pH 8 solutions fit perfectly the Langmuir model. The thermodynamic functions ΔG, ΔH, and ΔS characteristic to the adsorption of CrO42- ions from K2CrO4 solutions with pH = 8 were calculated. The active sites belonging to the AV-17(Cr) material were identified as jarosite type compounds of Cr(III). SEM images show that the Cr(III) compounds are present in the form of ultrafine particles located on the surface and within the bulk phase of the polymer granules. Comparative thermal degradation process of both the AV-17(Cr) and the AV-17(Cl) material was conducted in air and in an inert atmosphere (He). The thermal degradation mechanism of sorbent AV-17(Cr) and exchanger AV-17(Cl) is proposed. |
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Cuvinte-cheie Crosslinking, degradation, functional groups, Inorganic polymers, ion exchange, Ions, Isotherms, Particles (particulate matter), sorption, spectroscopy, Thermogravimetric analysi |
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