Energy band structure and Frenkel excitons in PbGa 2S 4
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STAMOV, Ivan, SYRBU, Nicolae, URSACHI, Veaceslav, PARVAN, Vladimir, ZALAMAI, Victor. Energy band structure and Frenkel excitons in PbGa 2S 4. In: Optics Communications, 2012, vol. 285, pp. 5198-5204. ISSN 0030-4018. DOI: https://doi.org/10.1016/j.optcom.2012.07.041
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Optics Communications
Volumul 285 / 2012 / ISSN 0030-4018

Energy band structure and Frenkel excitons in PbGa 2S 4

DOI:https://doi.org/10.1016/j.optcom.2012.07.041

Pag. 5198-5204

Stamov Ivan1, Syrbu Nicolae2, Ursachi Veaceslav3, Parvan Vladimir2, Zalamai Victor3
 
1 Tiraspol State University,
2 Technical University of Moldova,
3 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 16 noiembrie 2023


Rezumat

Optical reflection spectra are measured and calculated in PbGa 24 crystals in the region of resonances related to excitons with large oscillator strength and binding energy (Frenkel excitons). The splitting of the upper valence band in the center of the Brillouin zone due to crystal field (Δ cf) and spin orbit (Δ so) interaction are determined. Optical reflection spectra are measured and calculated according to Kramers-Kronig relations in the region of 3-6 eV in ⊥ and ∥ polarizations, and the optical constants n, k, ε 1 and ε 2 are determined. The observed electronic transitions in PbGa 24 crystals are discussed in the frame of theoretical energy band structure calculation for thiogallate crystals. 

Cuvinte-cheie
Band structure, Excitons, optical absorption, reflection, and luminescence spectra, Optical constants, Semiconductor compound