Impurity centers in ZnSe:Na crystals
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KOLIBABA, Gleb, NEDEOGLO, Dumitru, URSAKI, Veaceslav. Impurity centers in ZnSe:Na crystals. In: Journal of Luminescence, 2011, vol. 131, pp. 1966-1970. ISSN 0022-2313. DOI: https://doi.org/10.1016/j.jlumin.2011.03.069
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Journal of Luminescence
Volumul 131 / 2011 / ISSN 0022-2313

Impurity centers in ZnSe:Na crystals

DOI:https://doi.org/10.1016/j.jlumin.2011.03.069

Pag. 1966-1970

Kolibaba Gleb1, Nedeoglo Dumitru1, Ursaki Veaceslav2
 
1 Moldova State University,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 5 octombrie 2023


Rezumat

The influence of sodium impurity on photoluminescence (PL) spectra of ZnSe crystals doped in a growth process from a SeNa melt is investigated. It is shown that the introduction of the impurity results in emergence of emission bands in the PL spectra due to the recombination of exciton impurity complexes associated with both donors and hydrogen-like acceptors. Apart from that, four bands generated by donoracceptor pairs recombination and a band produced by electronic transitions from the conduction band to a shallow acceptor are discussed. As a result of the analysis it is concluded that Na impurity forms in ZnSe lattice NaZn hydrogen-like acceptors with activation energy of 105±3 meV, Nai donor centers with activation energy of 18±3 meV, as well as NaZnVSe and Na iNaZn associative donors with activation energy of 35±3 and 52±9 meV, respectively. 

Cuvinte-cheie
Associative complexes, Na impurity, p-ZnSe, photoluminescence, Shallow acceptors

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<creatorName>Ursachi, V.V.</creatorName>
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<title xml:lang='en'>Impurity centers in ZnSe:Na crystals</title>
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<publicationYear>2011</publicationYear>
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<subjects>
<subject>Associative complexes</subject>
<subject>Na impurity</subject>
<subject>p-ZnSe</subject>
<subject>photoluminescence</subject>
<subject>Shallow acceptors</subject>
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<date dateType='Issued'>2011-09-01</date>
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<description xml:lang='en' descriptionType='Abstract'><p>The influence of sodium impurity on photoluminescence (PL) spectra of ZnSe crystals doped in a growth process from a SeNa melt is investigated. It is shown that the introduction of the impurity results in emergence of emission bands in the PL spectra due to the recombination of exciton impurity complexes associated with both donors and hydrogen-like acceptors. Apart from that, four bands generated by donoracceptor pairs recombination and a band produced by electronic transitions from the conduction band to a shallow acceptor are discussed. As a result of the analysis it is concluded that Na impurity forms in ZnSe lattice Na<sub>Zn</sub>&nbsp;hydrogen-like acceptors with activation energy of 105&plusmn;3 meV, Na<sub>i</sub>&nbsp;donor centers with activation energy of 18&plusmn;3 meV, as well as Na<sub>Zn</sub>V<sub>Se</sub>&nbsp;and Na&nbsp;<sub>i</sub>Na<sub>Zn</sub>&nbsp;associative donors with activation energy of 35&plusmn;3 and 52&plusmn;9 meV, respectively.&nbsp;</p></description>
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