Purification of ZnSe crystals from electrically active background impurities by ytterbium doping
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RADEVICI, Ivan, SUSHKEVICH, Konstantin, SIRKELI, Vadim, HUHTINEN, Hannu, NEDEOGLO, Natalia, NEDEOGLO, Dumitru, PATURI, Petriina. Purification of ZnSe crystals from electrically active background impurities by ytterbium doping. In: Physica Status Solidi (B) Basic Research, 2014, vol. 251, pp. 1565-1569. ISSN 0370-1972. DOI: https://doi.org/10.1002/pssb.201451022
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Physica Status Solidi (B) Basic Research
Volumul 251 / 2014 / ISSN 0370-1972

Purification of ZnSe crystals from electrically active background impurities by ytterbium doping

DOI:https://doi.org/10.1002/pssb.201451022

Pag. 1565-1569

Radevici Ivan12, Sushkevich Konstantin2, Sirkeli Vadim2, Huhtinen Hannu1, Nedeoglo Natalia2, Nedeoglo Dumitru2, Paturi Petriina1
 
1 Wihuri Physical Laboratory, University of Turku,
2 Moldova State University
 
 
Disponibil în IBN: 15 septembrie 2023


Rezumat

Hall coefficient, electrical conductivity, and electron mobility are investigated for n-ZnSe:Yb single crystals with high concentration of electrically active background impurities ((ND-NA)>1.4×1017cm-3) in the temperature range from 4.2 to 300K. It is found that increasing concentration of Yb impurity in Zn+Yb melt from 0.03 to 4.00at.% decreases the concentration of shallow ND and deep NDeep donors, as well as the concentration of compensating acceptors NA by nearly 2 orders of magnitude. A quantitative manifestation of purification of the ZnSe:Yb samples from non-controlled background electrically active impurities and influence of this effect on changes in impurity band parameters and the temperature of electron gas degeneracy are shown. The most probable mechanism of the sample purification due to the formation of electrically neutral complexes based on ytterbium ions and background impurities of donor and acceptor types is discussed. 

Cuvinte-cheie
conductivity, doping, Hall effect, Ytterbium, ZnSe