Cobalt(II) and nickel(II) coordination compounds with 4-phenylthiosemicarbazidodiacetic acid dihydrazide: Synthesis and study
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LOZAN, Vasile, GORBACHEV, Mikhail, BOLOGA, Olga, GULYA, Aurelian. Cobalt(II) and nickel(II) coordination compounds with 4-phenylthiosemicarbazidodiacetic acid dihydrazide: Synthesis and study. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 1998, vol. 24, pp. 480-485. ISSN -.
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volumul 24 / 1998 / ISSN - /ISSNe 1070-3284

Cobalt(II) and nickel(II) coordination compounds with 4-phenylthiosemicarbazidodiacetic acid dihydrazide: Synthesis and study


Pag. 480-485

Lozan Vasile, Gorbachev Mikhail, Bologa Olga, Gulya Aurelian
 
Institute of Chemistry of the Academy of Sciences of Moldova
 
 
Disponibil în IBN: 6 septembrie 2023


Rezumat

The coordination compounds of the MLX2 · nH2O (M = Co2+, Ni2+, or Zn2+ and X = F-, Cl-, Br-, NO3-, or NCS-) type between cobalt(II), nickel(II), and zinc(II) and 4-phenylthiosemicarbazidodiacetic acid dihydrazide (C6H5)NHC(S)NHN(CH2CONHNH22(L) were synthesized. The 1H and 13C NMR spectra of the free and coordinated ligand in dimethyl sulfoxide were examined. The MM2 and CNDO/2 calculations of the geometrical and electronic structures of L were carried out