Porosification of III-V and II-VI semiconductor compounds
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MONAICO, Eduard, KOLIBABA, Gleb, NEDEOGLO, Dumitru, NIELSCH, Kornelius. Porosification of III-V and II-VI semiconductor compounds. In: Journal of Nanoelectronics and Optoelectronics, 2014, vol. 9, pp. 307-311. ISSN 1555-130X. DOI: https://doi.org/10.1166/jno.2014.1581
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Journal of Nanoelectronics and Optoelectronics
Volumul 9 / 2014 / ISSN 1555-130X

Porosification of III-V and II-VI semiconductor compounds

DOI:https://doi.org/10.1166/jno.2014.1581
CZU: 621.315.592

Pag. 307-311

Monaico Eduard12, Kolibaba Gleb3, Nedeoglo Dumitru3, Nielsch Kornelius1
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 Technical University of Moldova,
3 Moldova State University
 
 
Disponibil în IBN: 28 august 2023


Rezumat

We report on a comparative study of the pore growth during anodization of a narrow-bandgap III-V compound (InAs), a medium-bandgap III-V one (InP) and wide-bandgap II-VI semiconductors (ZnSe and Zn0.4 Cd0.6S). According to the obtained results, the morphology of the porous layers can be controlled by the composition of the electrolyte and the applied electrochemical parameters. It was evidenced that in the narrow bandgap semiconductor InAs it is difficult to control the mechanism of pore growth. Both current-line oriented pores and crystallographically oriented pores were produced in the medium-bandgap material InP. The electrochemical nanostructuring of wide-bandgap semiconductors realized in single crystalline high-conductivity samples evidenced only current-line oriented pores. This behavior is explained in terms of difference in the values of electronegativity of the constituent atoms and the degree of ionicity.

Cuvinte-cheie
Anodization, crystallographically oriented pores, current-line-oriented pores, Iconicity degree, Porous layer