An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule
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BREFUEL, Nicolas, DUHAYON, Carine, SHOVA, Sergiu, TUCHAGUES, Jean-Pierre M.. An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule. In: Chemical Communications, 2007, pp. 5223-5225. ISSN 1359-7345. DOI: https://doi.org/10.1039/b710734j
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Chemical Communications
/ 2007 / ISSN 1359-7345 /ISSNe 1364-548X

An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule

DOI:https://doi.org/10.1039/b710734j

Pag. 5223-5225

Brefuel Nicolas1, Duhayon Carine1, Shova Sergiu12, Tuchagues Jean-Pierre M.1
 
1 Laboratoire de Chimie de Coordination du CNRS, Toulouse,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 17 iulie 2023


Rezumat

Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeLB5(NCS)2]·trans-[FeL B5(NCS)2]}·CH3OH, 1, (LB5 = N,N′-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1, 3-diamine); the synthesis, X-ray structure, and magnetic and Mössbauer study of this unique exam

Cuvinte-cheie
EMTREE drug terms iron complex EMTREE medical terms article, chemical structure, complex formation, crystallization, isomer, magnetism, Mössbauer spectroscopy, synthesis

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<title xml:lang='en'>An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule</title>
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<publicationYear>2007</publicationYear>
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<subject>EMTREE drug terms
iron complex
EMTREE medical terms
article</subject>
<subject>chemical structure</subject>
<subject>complex formation</subject>
<subject>crystallization</subject>
<subject>isomer</subject>
<subject>magnetism</subject>
<subject>Mössbauer spectroscopy</subject>
<subject>synthesis</subject>
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<date dateType='Issued'>2007-06-01</date>
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<description xml:lang='en' descriptionType='Abstract'><p>Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeL<sup>B5</sup>(NCS)<sub>2</sub>]&middot;trans-[FeL&nbsp;<sup>B5</sup>(NCS)<sub>2</sub>]}&middot;CH<sub>3</sub>OH, 1, (L<sup>B5</sup>&nbsp;= N,N&prime;-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1, 3-diamine); the synthesis, X-ray structure, and magnetic and M&ouml;ssbauer study of this unique exam</p></description>
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