An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule

Brefuel Nicolas; Duhayon Carine; Shova Sergiu; Tuchagues Jean-Pierre M.

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SM ISO690:2012

BREFUEL, Nicolas, DUHAYON, Carine, SHOVA, Sergiu, TUCHAGUES, Jean-Pierre M.. An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule. In: Chemical Communications, 2007, pp. 5223-5225. ISSN 1359-7345. DOI: https://doi.org/10.1039/b710734j

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Chemical Communications

/ 2007 / ISSN 1359-7345 /ISSNe 1364-548X

An unprecedented co-crystal including a cis-high-spin and a trans-low-spin Fe^II complex molecule

DOI:https://doi.org/10.1039/b710734j

Pag. 5223-5225

Brefuel Nicolas¹, Duhayon Carine¹, Shova Sergiu¹², Tuchagues Jean-Pierre M.¹

¹ Laboratoire de Chimie de Coordination du CNRS, Toulouse,
² Institute of Applied Physics, Academy of Sciences of Moldova

Disponibil în IBN: 17 iulie 2023

Rezumat

Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeL^B5(NCS)₂]·trans-[FeL ^B5(NCS)₂]}·CH₃OH, 1, (L^B5 = N,N′-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1, 3-diamine); the synthesis, X-ray structure, and magnetic and Mössbauer study of this unique exam

Cuvinte-cheie
EMTREE drug terms iron complex EMTREE medical terms article, chemical structure, complex formation, crystallization, isomer, magnetism, Mössbauer spectroscopy, synthesis

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