| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 193 0 |
 SM ISO690:2012MELNYK, Silvia, PRODIUS, Denis, STOECKLI-EVANS, Helen Margaret, SHOVA, Sergiu, TURTA, Constantin. Synthesis and anti-tuberculosis activity of new hetero(Mn, Co, Ni)trinuclear iron(III) furoates. In: European Journal of Medicinal Chemistry, 2010, vol. 45, pp. 1465-1469. ISSN 0223-5234. DOI: https://doi.org/10.1016/j.ejmech.2009.12.053 |
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  European Journal of Medicinal Chemistry |
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| Volumul 45 / 2010 / ISSN 0223-5234 /ISSNe 1768-3254 | ||||||
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| DOI:https://doi.org/10.1016/j.ejmech.2009.12.053 | ||||||
| Pag. 1465-1469 | ||||||
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New hetero(μ3-oxo)trinuclear iron(III) furoates with the general formulas [Fe2MO(α-Fur)6(L)(H2O)2], where L = THF (1-3), DMF (4-5), M = Mn2+ (1, 4), Co2+ (2, 5), Ni2+ (3, 6) and [Fe2MO(α-Fur)6(3Cl-Py)3], where M = Mn2+ (7), Co2+ (8), Ni2+ (9); have been synthesised and investigated by Mössbauer and IR spectroscopies. The X-ray crystal structure has been determined for the 4 and 8 complexes, indicating that they are related to the monoclinic crystal system (P21/n) and have a structure typical of μ3-O-bridged trinuclear iron (III) compounds. The 57Fe Mössbauer spectra of microcrystalline samples of the compounds indicate the presence of high-spin iron (III) (S = 5/2) with a near symmetrical environments. The iron(III)-cobalt(II) containing compounds 2, 5 and 8 displayed MIC values between 0.83 ÷ 4.00 μg/mL. |
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| Cuvinte-cheie μ3-Oxo-heterotrinuclear cluster, Anti-tuberculosis activity, crystal structure |
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