Production of tartric acid from wine yeast via reactive extraction
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DUKA, Gh., MEREUTA, Aliona, GONTA, Maria, COJOCARU, Corneliu. Production of tartric acid from wine yeast via reactive extraction. In: Environmental Engineering and Management Journal, 2004, vol. 3, pp. 771-780. ISSN 1582-9596. DOI: https://doi.org/10.30638/eemj.2004.078
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Environmental Engineering and Management Journal
Volumul 3 / 2004 / ISSN 1582-9596

Production of tartric acid from wine yeast via reactive extraction

DOI:https://doi.org/10.30638/eemj.2004.078

Pag. 771-780

Duka Gh.1, Mereuta Aliona1, Gonta Maria1, Cojocaru Corneliu2
 
1 Moldova State University,
2 Gheorghe Asachi Technical University of Iasi
 
 
Disponibil în IBN: 13 aprilie 2023


Rezumat

The researches presented in this study include the optimization of the basic technological operations, while producing the tartric acid and the elaboration of a new procedure to obtain it from the wine yeast. Two basic technological operations were studied: the dissolution of the tartric compounds from the secondary wine products and the reactive extraction of the tartric acid from a watery milieu. Further on, the above-mentioned procedures were changed and improved using mathematical tools. Based on the experimental results, two empiric mathematical models were elaborated for the dissolution of the tartric compounds from the wine wastes and extraction of the tartric acid from a watery milieu, which offered the possibility to improve the performance of these procedures and to establish the optimal conditions in order to accomplish the listed procedures. The process of extraction of the tartric acid was performed using a system from the group of the secondary amines (Amberlite LA-2), that are soluble in the organic solvents (butyl acetate), that offered us a new way of separation of the tartric acid. The laws of the mechanism of the process of extraction have been studied both on a model and real system. A new method of crystallization of the tartric acid made from an azeotropic mixture formed at the introduction into the watery solution of the O-xyleinum, an organic solvent in which the tartric acid is practically unsolvable was proposed. When the extraction of the water from the system is made, the tartric acid starts to crystallize. As a consequence, the technological scheme of obtaining the acid from the wine yeast and the economical account in order to establish the cost price of 1kg of tartric acid acquired via the classic technique and the method of reactive extraction with a change of ions. 

The researches presented in this study include the optimization of the basic technological operations, while producing the tartric acid and the elaboration of a new procedure to obtain it from the wine yeast. Two basic technological operations were studied: the dissolution of the tartric compounds from the secondary wine products and the reactive extraction of the tartric acid from a watery milieu. Further on, the above-mentioned procedures were changed and improved using mathematical tools. Based on the experimental results, two empiric mathematical models were elaborated for the dissolution of the tartric compounds from the wine wastes and extraction of the tartric acid from a watery milieu, which offered the possibility to improve the performance of these procedures and to establish the optimal conditions in order to accomplish the listed procedures. The process of extraction of the tartric acid was performed using a system from the group of the secondary amines (Amberlite LA-2), that are soluble in the organic solvents (butyl acetate), that offered us a new way of separation of the tartric acid. The laws of the mechanism of the process of extraction have been studied both on a model and real system. A new method of crystallization of the tartric acid made from an azeotropic mixture formed at the introduction into the watery solution of the O-xyleinum, an organic solvent in which the tartric acid is practically unsolvable was proposed. When the extraction of the water from the system is made, the tartric acid starts to crystallize. As a consequence, the technological scheme of obtaining the acid from the wine yeast and the economical account in order to establish the cost price of 1kg of tartric acid acquired via the classic technique and the method of reactive extraction with a change of ions. 

Cuvinte-cheie
Amberlite LA-2, reactive extraction, Secondary wine products, Tartric acid, The modelling of the process