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 SM ISO690:2012KULCIŢKI, Veaceslav, SÎRBU (RĂDUCAN), Tatiana, UNGUR, Nikon. On the peculiarities of the ring contraction
reactions of homodrimanes via acid mediated epoxide rearrangement
. In: Chemistry Journal of Moldova, 2011, nr. 1(6), pp. 110-112. ISSN 1857-1727. |
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| Chemistry Journal of Moldova | ||||||
| Numărul 1(6) / 2011 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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| Pag. 110-112 | ||||||
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A selective rearrangement of a epoxi-homodrimanic substrate is described. Using fluorosulfonic acid at
low temperature leads by ring contraction to a perhydrindanic structure. On the contrary, using boron trifluoride-
diethyl ether at r.t. selectively brings about angular methyl migration.
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| Cuvinte-cheie terpenoids, epoxide, homodrimane, rearrangement, hydrindane |
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<meta name="citation_title" content="On the peculiarities of the ring contraction reactions of homodrimanes via acid mediated epoxide rearrangement "> <meta name="citation_author" content="Kulciţki Veaceslav"> <meta name="citation_author" content="Sîrbu (Răducan) Tatiana"> <meta name="citation_author" content="Ungur Nikon"> <meta name="citation_publication_date" content="2011/01/03"> <meta name="citation_journal_title" content="Chemistry Journal of Moldova"> <meta name="citation_volume" content="6"> <meta name="citation_issue" content="1"> <meta name="citation_firstpage" content="110"> <meta name="citation_lastpage" content="112"> <meta name="citation_pdf_url" content="https://ibn.idsi.md/sites/default/files/imag_file/On%20the%20peculiarities%20of%20the%20ring%20contraction.pdf">
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