On the peculiarities of the ring contraction reactions of homodrimanes via acid mediated epoxide rearrangement
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KULCIŢKI, Veaceslav, SÎRBU (RĂDUCAN), Tatiana, UNGUR, Nikon. On the peculiarities of the ring contraction reactions of homodrimanes via acid mediated epoxide rearrangement . In: Chemistry Journal of Moldova, 2011, nr. 1(6), pp. 110-112. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 1(6) / 2011 / ISSN 1857-1727 /ISSNe 2345-1688

On the peculiarities of the ring contraction reactions of homodrimanes via acid mediated epoxide rearrangement

Pag. 110-112

Kulciţki Veaceslav, Sîrbu (Răducan) Tatiana, Ungur Nikon
 
Institute of Chemistry of the Academy of Sciences of Moldova
 
 
Disponibil în IBN: 12 decembrie 2013


Rezumat

A selective rearrangement of a epoxi-homodrimanic substrate is described. Using fluorosulfonic acid at low temperature leads by ring contraction to a perhydrindanic structure. On the contrary, using boron trifluoride- diethyl ether at r.t. selectively brings about angular methyl migration.

Cuvinte-cheie
terpenoids, epoxide,

homodrimane, rearrangement, hydrindane

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<dc:creator>Kulciţki, V.N.</dc:creator>
<dc:creator>Sîrbu (Răducan), T..</dc:creator>
<dc:creator>Ungur, N.D.</dc:creator>
<dc:date>2011-01-03</dc:date>
<dc:description xml:lang='en'>A selective rearrangement of a epoxi-homodrimanic substrate is described. Using fluorosulfonic acid at
low temperature leads by ring contraction to a perhydrindanic structure. On the contrary, using boron trifluoride-
diethyl ether at r.t. selectively brings about angular methyl migration.
</dc:description>
<dc:source>Chemistry Journal of Moldova 6 (1) 110-112</dc:source>
<dc:subject>terpenoids</dc:subject>
<dc:subject>homodrimane</dc:subject>
<dc:subject>epoxide</dc:subject>
<dc:subject>rearrangement</dc:subject>
<dc:subject>hydrindane</dc:subject>
<dc:title>On the peculiarities of the ring contraction
reactions of homodrimanes via acid mediated epoxide rearrangement
</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
</oai_dc:dc>