Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
1005 2 |
Ultima descărcare din IBN: 2023-05-26 23:22 |
SM ISO690:2012 KULCIŢKI, Veaceslav, SÎRBU (RĂDUCAN), Tatiana, UNGUR, Nikon. On the peculiarities of the ring contraction
reactions of homodrimanes via acid mediated epoxide rearrangement
. In: Chemistry Journal of Moldova, 2011, nr. 1(6), pp. 110-112. ISSN 1857-1727. |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
Chemistry Journal of Moldova | ||||||
Numărul 1(6) / 2011 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
|
||||||
Pag. 110-112 | ||||||
|
||||||
Descarcă PDF | ||||||
Rezumat | ||||||
A selective rearrangement of a epoxi-homodrimanic substrate is described. Using fluorosulfonic acid at
low temperature leads by ring contraction to a perhydrindanic structure. On the contrary, using boron trifluoride-
diethyl ether at r.t. selectively brings about angular methyl migration.
|
||||||
Cuvinte-cheie terpenoids, epoxide, homodrimane, rearrangement, hydrindane |
||||||
|
Dublin Core Export
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Kulciţki, V.N.</dc:creator> <dc:creator>Sîrbu (Răducan), T..</dc:creator> <dc:creator>Ungur, N.D.</dc:creator> <dc:date>2011-01-03</dc:date> <dc:description xml:lang='en'>A selective rearrangement of a epoxi-homodrimanic substrate is described. Using fluorosulfonic acid at low temperature leads by ring contraction to a perhydrindanic structure. On the contrary, using boron trifluoride- diethyl ether at r.t. selectively brings about angular methyl migration. </dc:description> <dc:source>Chemistry Journal of Moldova 6 (1) 110-112</dc:source> <dc:subject>terpenoids</dc:subject> <dc:subject>homodrimane</dc:subject> <dc:subject>epoxide</dc:subject> <dc:subject>rearrangement</dc:subject> <dc:subject>hydrindane</dc:subject> <dc:title>On the peculiarities of the ring contraction reactions of homodrimanes via acid mediated epoxide rearrangement </dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>