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SM ISO690:2012 COVACI, Ecaterina. Thermodynamic and kinetic studies of potassium bitartrate sedimentation into young wines during the cold stabilization. In: Tendinţe contemporane ale dezvoltării ştiinţei: viziuni ale tinerilor cercetători, Ed. 4, 10 martie 2015, Chișinău. Chișinău, Republica Moldova: Universitatea Academiei de Ştiinţe a Moldovei, 2015, Ediția 4, p. 47. |
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Tendinţe contemporane ale dezvoltării ştiinţei: viziuni ale tinerilor cercetători Ediția 4, 2015 |
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Conferința "Tendinţe contemporane ale dezvoltării ştiinţei: viziuni ale tinerilor cercetători" 4, Chișinău, Moldova, 10 martie 2015 | ||||||
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Pag. 47-47 | ||||||
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Generally, the solubility of potassium bitartrate (KHT) is dependent primarily upon the: alcohol content, pH, the temperature of the storage, the presence of colloids, etc. [1]. In young wines, KHT is always present in supersaturating concentrations and crystallizes spontaneously. The cooling technique of young wines has found commercial application [2]. Investigations have been conducted on two young wines Chardonnay and Pinot Noir varieties of vintage 2014. Data obtained of physic-chemical analyses of the wine were used to calculate: the thermodynamic and the Arrhenius parameters of the process according to the methodology proposed in literature [3]. Based on thermodynamics, negative ΔG° and ΔH° values and positive ΔS° values give a spontaneous process at lower temperatures with an easier KHT precipitation. The value of kinetics parameters decreases with increasing temperature treatments, the heat factor and of composition have a decisive influence on the reaction rate. The results show that the precipitation reaction of KHT in wine is characterized through a medium activation energy and a high frequency factor, which explains the significant rate reaction of these compounds in young white and red wines. In addition, the studied reaction is not limited to the diffusion factors, but those kinetics. |