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 SM ISO690:2012ARION, Vladimir, PALAMARCIUC, Oleg, SHOVA, Sergiu, NOVITSKY, Ghenadie, RAPTA, Peter. Iron(III) complexes with ditopic macrocycles bearing crown-ether and bis(salicylidene) isothiosemicarbazide moieties. In: Journal of the Serbian Chemical Society, 2023, vol. 88, pp. 1205-1222. ISSN 0352-5139. DOI: https://doi.org/10.2298/JSC230607065A |
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  Journal of the Serbian Chemical Society |
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| Volumul 88 / 2023 / ISSN 0352-5139 /ISSNe 1820-7421 | ||||||
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| DOI:https://doi.org/10.2298/JSC230607065A | ||||||
| Pag. 1205-1222 | ||||||
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The main aims of this work were the synthesis and characterization of iron(III) complexes with a ditopic ligand H2L consisting of a bis(salicylidene)isothiosemicarbazide moiety with a N2O2 binding site and a crown-ether (O6) moiety. A series of high-spin iron(III) complexes, i.e., [FeIIILClBa(CH3OH)(H2O)0.5(ZnCl4)] (1), [FeIIILCl] (2), [FeIIIL(N3)] (3) and [(FeIIIL)2O] (4), were synthesized. The complexes were characterized by mass spectrometry, IR and UV–Vis spectroscopy, variable temperature (VT) magnetic susceptibility measurements, Mössbauer spectroscopy, single crystal X-ray diffraction and cyclic voltammetry. |
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| Cuvinte-cheie bi-compartmental ligand, Iron(III), magnetism, Mössbauer |
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