The correlation between the composition, morphology, and properties of Fe-W alloy coatings containing up to 29 at % tungsten was investigated by means of scanning electron microscopy, X-ray diffraction analysis, and the wear resistance and nanohardness measurements. The coatings were deposited from the citrate-ammonia bath at a direct current, the current densities were ranged from 10 to 100 mA/cm². It is shown that, in contrast to metallurgical iron, the Fe-W coatings are nanocrystalline (amorphous, the grain size is 3.0-4.0 nm). This structure of alloys allows us to produce the coatings with a nanohardness of ∼ 13 GPa, which is comparable to the electrolytic chromium coatings. The study of wear resistance of thus obtained coatings reveals their oxidation in the course of dry friction; as a result, the oxygen content in the debris increases by 2-3 times, and the wear volume due to the tribooxidation exceeds that for similar hard Co-W and electrolytic chromium coatings.