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 SM ISO690:2012BOUROSH, Pavlina, COROPCEANU, Eduard, SIMONOV, Yurii A., GDANIEC, Maria, BOLOGA, Olga, GERBELEU, Nicolae. Cobalt(III) α-dimethylglyoximates [Co(DH)2(Py) 2]2SiF6·10H2O and [Co(DH)2(Thio)2]2SiF6·2H 2O·C2H5OH: Synthesis and structure. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2002, vol. 28, pp. 647-655. ISSN -. DOI: https://doi.org/10.1023/A:1020095101054 |
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  Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
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| Volumul 28 / 2002 / ISSN - /ISSNe 1070-3284 | ||||||
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| DOI:https://doi.org/10.1023/A:1020095101054 | ||||||
| Pag. 647-655 | ||||||
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[Co(DH)2(Py)2]2SiF 6·10H2O and [Co(DH)2(Thio) 2]2SiF6·2H2O·C 2H5OH complexes are synthesized and characterized by X-ray diffraction analysis. Two radicals of α-glyoxime linked by hydrogen O-H⋯O bonds lie in the equatorial plane of the octahedral Co(III) complexes. Intramolecular (π-π and N-H⋯O) and intermolecular (O-H⋯F, O-H⋯O, N-H⋯F, N-H⋯O, N-H⋯S) interactions are discovered in the crystal. The influence of nonvalence interactions on the structures is discussed. |
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| Cuvinte-cheie EMTREE drug terms alpha dimethylglyoximate, alpha glyoxime, cobalt complex, glyoxal derivative, hydrogen, unclassified drug EMTREE medical terms article, chemical interaction, Crystal, crystal structure, hydrogen bond, synthesis, X ray diffraction |
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