Articolul precedent |
Articolul urmator |
442 0 |
SM ISO690:2012 OSTROVSKY, Sergei M., KLOKISHNER, Sophia I.. Modeling of charge transfer induced spin transition in a linear {FeCoFe} complex. In: IFMBE Proceedings: . 4th International Conference on Nanotechnologies and Biomedical Engineering, Ed. 4, 18-21 septembrie 2019, Chişinău. Switzerland: Springer Nature Switzerland AG, 2020, Ediția 4, Vol.77, pp. 43-46. ISBN 978-303031865-9. ISSN 16800737. DOI: https://doi.org/10.1007/978-3-030-31866-6_9 |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
IFMBE Proceedings Ediția 4, Vol.77, 2020 |
|||||||
Conferința "Conference on Nanotechnologies and Biomedical Engineering" 4, Chişinău, Moldova, 18-21 septembrie 2019 | |||||||
|
|||||||
DOI:https://doi.org/10.1007/978-3-030-31866-6_9 | |||||||
Pag. 43-46 | |||||||
|
|||||||
Descarcă PDF | |||||||
Rezumat | |||||||
The magnetic behavior of the {[FeTp(CN)3]2Co(Meim)4} · 6H2O compound is examined. Since the observed charge transfer induced spin transition in this compound is accompanied by electronic density redistribution, the theoretical model includes the electron transfer between the Fe and Co ions and two types of cooperative interactions, namely, the electron-deformational and dipole-dipole interactions. It is demonstrated that at low temperatures the spin transformation in the compound under study is accompanied by the appearance of macroscopic polarization. The developed model gives a quite good explanation of the observed effective magnetic moment. |
|||||||
Cuvinte-cheie Charge transfer induced spin transition (CTIST), Cooperative dipole-dipole interaction, Electron transfer, Macroscopic polarization |
|||||||
|