Electrodeposition of Nanocrystalline Co W Coatings from Citrate Electrolytes Under Controlled Hydrodynamic Conditions Part 3: The Micro and Macrodistribution of the Deposition Rates, the Structure, and the Mechanical Properties
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SILKIN, Serghei, BELEVSKII, Stanislav, GRADINAR, A., PETRENKO, Vladimir, DIKUSAR, Aleksandr , YAKOVEC, I. , TSYNTSARU, Natalia. Electrodeposition of Nanocrystalline Co W Coatings from Citrate Electrolytes Under Controlled Hydrodynamic Conditions Part 3: The Micro and Macrodistribution of the Deposition Rates, the Structure, and the Mechanical Properties . In: Surface Engineering and Applied Electrochemistry, 2010, nr. 3(46), pp. 206-214. ISSN 1068-3755.
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Surface Engineering and Applied Electrochemistry
Numărul 3(46) / 2010 / ISSN 1068-3755 /ISSNe 1934-8002

Electrodeposition of Nanocrystalline Co W Coatings from Citrate Electrolytes Under Controlled Hydrodynamic Conditions Part 3: The Micro and Macrodistribution of the Deposition Rates, the Structure, and the Mechanical Properties

Pag. 206-214

Silkin Serghei1, Belevskii Stanislav2, Gradinar A.1, Petrenko Vladimir2, Yakovec I. , Tsyntsaru Natalia, Dikusar Aleksandr 2
 
1 T.G. Shevchenko State University of Pridnestrovie, Tiraspol,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 13 decembrie 2013


Rezumat

Using a Hull cell with a rotating cylindrical electrode (RCE), the effect of the hydrodynamic conditions on the deposition rate and its micro and macrodistribution and the composition and microhardness of the cobalt–tungsten coatings deposited from a citrate electrolyte containing cobalt sulphate (0.2 mol/l) and sodium tungstate (0.2 mol/l) at pH = 6.7 and the solution temperature of 60°C in the Re numbers range of 0 – 3000 is examined. It is shown that the hydrodynamic deposition conditions have no effect whatsoever on the surface roughness, but they slightly influence the electrolyte’s throwing power. The correlation between the intensity of the hydrodynamic flows, the deposition rate (due to the current efficiency’s increase), and the composition of the coatings (along with their distribution over the surface) is established. It is shown that certain modes of the process at a high deposition rate make it possible to reach a high uniformity of the coating’s composition with a high tungsten content, which results in obtaining the maximum surface microhardness.