Characterization of potassium carbonate solutions promoted by ethylenediamine and triethylenetetramine. Density of aqueous solutions: measuring and correlation
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TATARU-FARMUS, Ramona Elena, HULTUANA, Elisabeta, APOSTOLESCU, Nicolae, LISĂ, Gabriela Apreotesei, HARJA, Maria. Characterization of potassium carbonate solutions promoted by ethylenediamine and triethylenetetramine. Density of aqueous solutions: measuring and correlation. In: Achievements and perspectives of modern chemistry, 9-11 octombrie 2019, Chişinău. Chisinau, Republic of Moldova: Tipografia Academiei de Ştiinţe a Moldovei, 2019, p. 194. ISBN 978-9975-62-428-2.
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Achievements and perspectives of modern chemistry 2019
Conferința "International Conference "Achievements and perspectives of modern chemistry""
Chişinău, Moldova, 9-11 octombrie 2019

Characterization of potassium carbonate solutions promoted by ethylenediamine and triethylenetetramine. Density of aqueous solutions: measuring and correlation


Pag. 194-194

Tataru-Farmus Ramona Elena, Hultuana Elisabeta, Apostolescu Nicolae, Lisă Gabriela Apreotesei, Harja Maria
 
Gheorghe Asachi Technical University of Iasi
 
 
Disponibil în IBN: 11 noiembrie 2019


Rezumat

Potassium carbonate solution (K2CO3) is a widely used solvent for CO2 removal due to the low toxicity, low tendency of degradation, less energy requirement, high solubility in carbonate / bicarbonate system and other concerns asthe corrosion. For absorption, an aqueous solution of 20-40% K2CO3 is used as close as possible to the saturation without the phenomenon of crystallization [1,2,3]. Since the rate of CO2 absorption is relatively slow in K2CO3, the use of various promoters has been required. In this work, ethylenediamine (EDA) and triethylenetetramine (TETA) were chosen as rate promoter candidates. Prior to the experimental determinations specific to the absorption process, all the physical properties involved must be known: the viscosity and density of the solution, the CO2 diffusion coefficient in the amine solution, as well as the Henry constant for CO2 in the amine solution [2,3]. The densities of the ternary aqueous solutions (K2CO3-Amine-H2O) have been measured for a blending 25 wt % potassium carbonate, amine concentrations between 1 and 10 wt %, at atmospheric pressure and temperatures from 303 K to 343 K (Figure). The densities for each solution have been measured with an Anton Paar digital vibrating glass tube densimeter, DMA 4500 model [3]. The experimental data have been correlated with temperature through a semiempirical equation with three coefficients which depend on the concentration and on the amine type with the equation p = a+bT+cT2 and the constants a, b, c have been identified by regression.