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Ultima descărcare din IBN: 2021-11-16 14:22 |
![]() WANG, Qiu-Hong, DENG, Jun, SUN, Jinhua, SHU, Chi-Min, LI, Haitao, LAI, Wangbin, CAO, Chen-Rui. Comparative study on combustion characteristics of zirconium particles coated with ferrite nanoparticles. In: Central and Eastern European Conference on Thermal Analysis and Calorimetry, Ed. 4, 28-31 august 2017, Chişinău. Germany: Academica Greifswald, 2017, Editia 4, p. 392. ISBN 978-3-940237-47-7. |
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Central and Eastern European Conference on Thermal Analysis and Calorimetry Editia 4, 2017 |
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Conferința "Central and Eastern European Conference" 4, Chişinău, Moldova, 28-31 august 2017 | ||||||
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Pag. 392-392 | ||||||
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Rezumat | ||||||
Zirconium metal powder is vastly used in aerospace and military as a metal fuel because of its high combustion rate and heat. To comply with the special requirements for aerospace and military applications, zirconium particles are coated respectively with ferrite nanoparticles–FeOOH, Fe2O3, Fe3O4 nanoparticles to form a core-shell structure [1]. This process alters the combustion performance of the coated zirconium dust. In this study, scanning electron microscopy, X–ray diffraction, thermogravimetry and differential scanning calorimetry are used to examine the micromorphology, phase composition, crystal structure, thermal stability and reactivity of the three kinds of coated zirconium particles [2,3]. The combustion behaviour of FeOOH–coated zirconium particles, Fe2O3–coated zirconium particles, Fe3O4–coated zirconium particles in the air is explored and presented comparatively. It was concluded that with the coating layer of coated zirconium particles generating a replacement reaction with the inner core zirconium [4,5]. The inner zirconium induced an oxidation-reduction reaction with oxygen and Fe2+ was oxidised at high temperatures. |
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Cuvinte-cheie Metal powder, Ferrite nanoparticles, Coated zirconium dust, Replacement reaction, Oxidation-reduction reaction |
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