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![]() DINCA, Alina S., MINDRU, Alexei, DRAGANCEA, Diana, TISEANU, Carmen D., SHOVA, Sergiu, CORNIA, Samuele, CARRELLA, Luca M., RENTSCHLER, Eva, AFFRONTE, M., ANDRUH, Marius. Aggregation of [Ln III 12] clusters by the dianion of 3-formylsalicylic acid. Synthesis, crystal structures, magnetic and luminescence properties. In: Dalton Transactions, 2019, nr. 5(48), pp. 1700-1708. ISSN 1477-9226. DOI: https://doi.org/10.1039/c8dt04602f |
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Dalton Transactions | |
Numărul 5(48) / 2019 / ISSN 1477-9226 /ISSNe 1477-9234 | |
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DOI:https://doi.org/10.1039/c8dt04602f | |
Pag. 1700-1708 | |
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Three isostrucutral dodecanuclear clusters with the general formula [Ln12(fsa)12(μf3-OH)12(DMF)12]·nDMF (fsa2- is the dianion of 3-formylsalicylic acid; Ln = Eu 1, Gd 2, Dy 3) have been obtained from the reaction of fromylsalicyclic acid (H2fsa), tetrabutylammonium hydroxide and Ln(NO3)3·6H2O in methanol/DMF. Their structure consists of four vertex-sharing heterocubanes. Each heterocubane unit is assembled from four LnIII ions, three μ3-OH groups and one μ3-oxygen atom arising from the fsa2- carboxylato group. The photophysical properties of the europium derivative investigated at both 300 and 80 K sustain a relative intense emission obtained under low power LED excitation at 420 nm. The dysprosium derivative shows a SMM behavior with an effective energy barrier Ueff of 22.9 cm-1, while the thermodynamical properties of Gd12 confirm a large magnetocaloric effect: S(7 T) - S(0 T) = 20R = 166 J mol-1 K), typical for isotropic GdIII derivatives, with ΔS = S(7 T) - S(0 T) = 1.7R for each GdIII ion. |
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<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Dinca, A.</dc:creator> <dc:creator>Mindru, A.</dc:creator> <dc:creator>Dragancea, D.P.</dc:creator> <dc:creator>Tiseanu, C.</dc:creator> <dc:creator>Şova, S.G.</dc:creator> <dc:creator>Cornia, S.</dc:creator> <dc:creator>Carrella, L.</dc:creator> <dc:creator>Rentschler, E.</dc:creator> <dc:creator>Affronte, M.</dc:creator> <dc:creator>Andruh, M.</dc:creator> <dc:date>2019-02-04</dc:date> <dc:description xml:lang='en'><p>Three isostrucutral dodecanuclear clusters with the general formula [Ln<sub>12</sub>(fsa)<sub>12</sub>(μf<sub>3</sub>-OH)<sub>12</sub>(DMF)<sub>12</sub>]·nDMF (fsa<sup>2-</sup> is the dianion of 3-formylsalicylic acid; Ln = Eu 1, Gd 2, Dy 3) have been obtained from the reaction of fromylsalicyclic acid (H<sub>2</sub>fsa), tetrabutylammonium hydroxide and Ln(NO<sub>3</sub>)<sub>3</sub>·6H<sub>2</sub>O in methanol/DMF. Their structure consists of four vertex-sharing heterocubanes. Each heterocubane unit is assembled from four Ln<sup>III</sup> ions, three μ<sub>3</sub>-OH groups and one μ<sub>3</sub>-oxygen atom arising from the fsa<sup>2-</sup> carboxylato group. The photophysical properties of the europium derivative investigated at both 300 and 80 K sustain a relative intense emission obtained under low power LED excitation at 420 nm. The dysprosium derivative shows a SMM behavior with an effective energy barrier U<sub>eff</sub> of 22.9 cm<sup>-1</sup>, while the thermodynamical properties of Gd<sub>12</sub> confirm a large magnetocaloric effect: S(7 T) - S(0 T) = 20R = 166 J mol<sup>-1</sup> K), typical for isotropic Gd<sup>III</sup> derivatives, with ΔS = S(7 T) - S(0 T) = 1.7R for each Gd<sup>III</sup> ion.</p></dc:description> <dc:identifier>10.1039/c8dt04602f</dc:identifier> <dc:source>Dalton Transactions 48 (5) 1700-1708</dc:source> <dc:title>Aggregation of [Ln III 12] clusters by the dianion of 3-formylsalicylic acid. Synthesis, crystal structures, magnetic and luminescence properties</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>