Crystal structure and characterization of neutral cobalt(III) 2,3-pyridinedicarboxylate complex

Terenti Natalia; Ferbinteanu  Marilena; Lazaresku Ana

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1036

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2023-07-20 12:34

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547 (520)

Chimie organică (484)

SM ISO690:2012

TERENTI, Natalia, FERBINTEANU, Marilena, LAZARESKU, Ana. Crystal structure and characterization of neutral cobalt(III) 2,3-pyridinedicarboxylate complex. In: Chemistry Journal of Moldova, 2018, nr. 1(13), pp. 24-29. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2017.371

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Chemistry Journal of Moldova

Numărul 1(13) / 2018 / ISSN 1857-1727 /ISSNe 2345-1688

Crystal structure and characterization of neutral cobalt(III) 2,3-pyridinedicarboxylate complex

DOI:https://doi.org/10.19261/cjm.2017.371

CZU: 547

Pag. 24-29

Terenti Natalia¹, Ferbinteanu Marilena², Lazaresku Ana¹

¹ Institute of Chemistry of the Academy of Sciences of Moldova,
² University of Bucharest

Disponibil în IBN: 6 iulie 2018

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Rezumat

A new Co(III) complex [Coⁱⁱⁱ(2,3-pdcH)3]·3H2O, (2,3-pdcH2 - 2,3-pyridinedicarboxylic acid) has been synthesized from a Co(II) salt at room temperature by using (NH4)2S2O8 as oxidant. The complex was characterized by elemental analysis, IR and UV-Vis spectroscopy, X-ray diffraction and thermogravimetric analyses. The complex crystallizes in the monoclinic space group P21/c. The crystal structure reveals a homoleptic complex with a distorted octahedral geometry, where the ligand acts as a monodeprotonated N, O-chelating anion

Cuvinte-cheie
Co(III) complex, 2, 3-pyridinedicarboxylic acid, thermal analysis, X-ray diffraction.

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